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Syntheses of 2,2'-bibenzo[7]annulenes by double Au-catalyzed sequential activation of propargylic carboxylates

Title
Syntheses of 2,2'-bibenzo[7]annulenes by double Au-catalyzed sequential activation of propargylic carboxylates
Author
오창호
Keywords
Cyclization; Gold catalyst; Benzo[7]annulene; Propargyl carboxylate; Bisbenzoannulene
Issue Date
2016-08
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON, v. 72, NO. 40, Page. 6113-6117
Abstract
We previously reported a novel Au-catalyzed sequential activation of two different propargyl carboxylates to 6-methylene-6H-benzo[7]annulene-5,8-diyl dicarboxylates. This reaction has been extended to syntheses of highly functionalized 2,2'-bibenzo[7]annulenes with four biphenyls bearing two sets of different propargyl carboxylates. (C) 2016 Elsevier Ltd. All rights reserved.
URI
https://www.sciencedirect.com/science/article/pii/S0040402016307189https://repository.hanyang.ac.kr/handle/20.500.11754/76340
ISSN
0040-4020
DOI
10.1016/j.tet.2016.07.060
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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