Dehydrogenation-driven Li metal-free prelithiation for high initial efficiency SiO-based lithium storage materials
- Title
- Dehydrogenation-driven Li metal-free prelithiation for high initial efficiency SiO-based lithium storage materials
- Author
- 김한수
- Keywords
- SiO; Lithium-ion batteries; Lithium hydride; Initial Coulombic efficiency; Lithiation
- Issue Date
- 2021-11
- Publisher
- ELSEVIER
- Citation
- NANO ENERGY, v. 89, article no. 106378, Page. 1-11
- Abstract
- Silicon monoxide (SiO) based materials are the most widely used high-capacity anode materials for commercialized lithium-ion batteries. However, their low initial Coulombic efficiency (ICE) hinders their full potential as anode materials for lithium-ion batteries. Here, we demonstrate that Li metal-free dehydrogenation-driven prelithiation employing lithium hydride (LiH) could improve the ICE of SiO up to 90.5%. Lithium liberated from LiH served as a source for preemptive formation of lithium silicate phases that are the main reason for the poor ICE of SiO, leading to three-dimensionally networked Si/lithium silicate nanocomposites, which were visualized by laser-assisted atom probe tomography (LA-APT) and scanning transmission electron microscopy (STEM). The prelithiated SiO delivered a capacity of 1203 mAh g−1 with an ICE of 90.5% without any degradation in other electrochemical performance. The improved ICE of prelithiated SiO made possible to enhance the energy density of full cell (37 mAh) by 50% compared to that adopting pristine SiO with an excellent cycle performance over 800 cycles. © 2021 Elsevier Ltd
- URI
- https://www.sciencedirect.com/science/article/pii/S2211285521006339?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/178322
- ISSN
- 2211-2855;2211-3282
- DOI
- 10.1016/j.nanoen.2021.106378
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ENERGY ENGINEERING(에너지공학과) > Articles
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