Isothermal and non-isothermal sublimation kinetics of zirconium tetrachloride (ZrCl4) for producing nuclear grade Zr
- Title
- Isothermal and non-isothermal sublimation kinetics of zirconium tetrachloride (ZrCl4) for producing nuclear grade Zr
- Author
- 박주현
- Keywords
- Inorganic compounds; Thermogravimetric analysis; Phase transitions; Thermal properties; Thermodynamic properties; Transport properties
- Issue Date
- 2014-02
- Publisher
- Elsevier BV
- Citation
- Materials Chemistry and Physics, v. 143, NO. 3, Page. 1075-1081
- Abstract
- Sublimation of ZrCl4 is important for the production of nuclear grade metallic Zr in Kroll's process. The sublimation kinetics of ZrCl4 was investigated by thermogravimetric analysis under both isothermal and non-isothermal conditions. The sublimation rate of ZrCl4 increased with increasing temperature under isothermal conditions. ZrCl4 sublimation was confirmed to be a zero-order process under isothermal conditions, whereas it was first-order kinetics under non-isothermal conditions. The activation energy of ZrCl4 sublimation under isothermal conditions was 21.7 kJ mol(-1). The activation energy for non-isothermal sublimation was 101.4 kJ mol(-1) and 108.1 kJ mol(-1) with the Kissinger method and Flynn-Wall-Ozawa method, respectively. These non-isothermal activation energies were very close to the heat of sublimation (103.3 kJ mol(-1)). Sublimation occurs by two elementary steps: surface reaction and desorption. Therefore, the overall activation energy of ZrCl4 sublimation is 104.8 (+/- 3.4) kJ mol(-1). The activation energy of the surface reaction and desorption steps are proposed to be 83.1 kJ mol(-1) and 21.7 kJ mol(-1), respectively. (C) 2013 Elsevier B.V. All rights reserved.
- URI
- https://www.sciencedirect.com/science/article/pii/S0254058413007967?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/175937
- ISSN
- 0254-0584;1879-3312
- DOI
- 10.1016/j.matchemphys.2013.11.007
- Appears in Collections:
- COLLEGE OF ENGINEERING SCIENCES[E](공학대학) > MATERIALS SCIENCE AND CHEMICAL ENGINEERING(재료화학공학과) > Articles
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