Growth Processes and Reductive Desorption Behaviors of 4-Fluorobenzenethiol Self-Assembled Monolayers on Au(111)
- Title
- Growth Processes and Reductive Desorption Behaviors of 4-Fluorobenzenethiol Self-Assembled Monolayers on Au(111)
- Author
- 노재근
- Keywords
- Self-Assembled Monolayers; 4-Fluorobenzenethiol; Growth Process; Phase Transition; Reductive Desorption; Scanning Tunneling Microscopy
- Issue Date
- 2020-08
- Publisher
- AMER SCIENTIFIC PUBLISHERS
- Citation
- JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v. 20, no. 8, page. 4955-4960
- Abstract
- Growth processes and electrochemical behaviors of 4-fluorobenzenethiol (4-FBT) self-assembled monolayers (SAMs) on Au(111) prepared by vapor deposition at 323 K were examined using scanning tunneling microscopy (STM) and cyclic voltammetry (CV). STM imaging revealed that 4-FBT SAMs at the initial growth stage (deposition for 1 min) were mainly composed of bright molecular aggregates and liquid-like disordered phase. After longer deposition for 3 min, 4-FBT SAMs had three distinct surface features: a few molecular aggregates, small ordered domains, and disordered phase. These small ordered domains with sizes ranging from 5 to 10 nm had a (4 x root 3)R30 degrees packing structure. As deposition time increased to 24 h, long-range ordered domains larger than 40 nm were formed on Au(111) surfaces. From this STM study, we demonstrate that phase transitions of 4-FBT SAMs on Au(111) occur from molecular aggregates to large ordered domains via formation of small ordered domains as deposition time increases. CV measurements showed reductive desorption peaks for 4-FBT SAMs in the range of -638 similar to -648 mV regardless of SAM morphology, suggesting that S-Au binding strength of 4-FBT SAMs on Au electrodes is a dominant factor for electrochemical stability.
- URI
- https://www.ingentaconnect.com/content/asp/jnn/2020/00000020/00000008/art00055;jsessionid=2elmtinkr1r6l.x-ic-live-01https://repository.hanyang.ac.kr/handle/20.500.11754/170276
- ISSN
- 1533-4880; 1533-4899
- DOI
- 10.1166/jnn.2020.17852
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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