Thiophene backbone-based polymers with electron-withdrawing pendant groups for application in organic thin-film transistors
- Title
- Thiophene backbone-based polymers with electron-withdrawing pendant groups for application in organic thin-film transistors
- Author
- 장재영
- Keywords
- BAND-GAP POLYMERS; CONJUGATED POLYMERS; OPTICAL-PROPERTIES; STABILITY; SEMICONDUCTORS; ORIENTATION; TEMPERATURE; PERFORMANCE; COPOLYMERS; EFFICIENCY
- Issue Date
- 2020-06
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- NEW JOURNAL OF CHEMISTRY, v. 44, no. 22, page. 9321-9327
- Abstract
- Two thiophene backbone-based hole-transporting polymers, namely, poly[(2,2 '-bithiophene-5,5 '-diyl)-alt-(5,7-bis(2-butyloctyl)-4H,8H-benzo[1,2-c:4,5-c ']dithiophene-4,8-dione-1,3-diyl)] (PT2-BDD) and poly[(3,3 '-difluoro-[2,2 '-bithiophene]-5,5 '-diyl)-alt-(5,7-bis(2-butyloctyl)-4H,8H-benzo[1,2-c:4,5-c ']dithiophene-4,8-dione-1,3-diyl)] (PF2-BDD), were prepared by using electron-withdrawing pendant groups such as ketone and fluorine moieties. They both exhibited a planar backbone with efficient pi conjugation, which is suitable for hole transport in organic thin-film transistors (OTFTs). However, the fluorinated one (i.e., PF2-BDD), despite its perfect backbone planarity and strong intra- and intermolecular interactions, could not enhance the OTFT performance; due to its solvent resistance, electron negativity, and random orientation, PF2-BDD showed 10 times lower hole mobility than the non-fluorinated polymer (i.e., PT2-BDD). Nonetheless, the two-dimensional grazing incidence X-ray diffraction and temperature-dependent absorption spectra of the synthesized polymers provided crucial information to understand the relationship between their hole transport behavior and molecular structure.
- URI
- https://pubs.rsc.org/en/content/articlelanding/2020/NJ/D0NJ01080Dhttps://repository.hanyang.ac.kr/handle/20.500.11754/168853
- ISSN
- 1144-0546; 1369-9261
- DOI
- 10.1039/d0nj01080d
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ENERGY ENGINEERING(에너지공학과) > Articles
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