Microstructural control of new intercalation layered titanoniobates with large and reversible d-spacing for easy Na+ ion uptake
- Title
- Microstructural control of new intercalation layered titanoniobates with large and reversible d-spacing for easy Na+ ion uptake
- Author
- 송태섭
- Keywords
- ANODE MATERIAL; ELECTROCHEMICAL-BEHAVIOR; ELECTRODE MATERIALS; ENERGY-STORAGE; ANATASE TIO2; SODIUM; BATTERIES; LITHIUM; OXIDES; PHASES
- Issue Date
- 2017-10
- Publisher
- AMER ASSOC ADVANCEMENT SCIENCE
- Citation
- SCIENCE ADVANCES, v. 3, no. 10, Article no. e1700509
- Abstract
- Key issues for Na-ion batteries are the development of promising electrode materials with favorable sites for Na+ ion intercalation/deintercalation and an understanding of the reaction mechanisms due to its high activation energy and poor electrochemical reversibility. We first report a layered H0.43Ti0.93Nb1.07O5 as a new anode material. This anode material is engineered to have dominant (200) and (020) planes with both a sufficiently large d-spacing of similar to 8.3 angstrom and two-dimensional ionic channels for easy Na+ ion uptake, which leads to a small volume expansion of similar to 0.6 angstrom along the c direction upon Na insertion (discharging) and the lowest energy barrier of 0.19 eV in the [020] plane among titanium oxide-based materials ever reported. The material intercalates and deintercalates reversibly 1.7 Na ions (similar to 200 mAh g(-1)) without a capacity fading in a potential window of 0.01 to 3.0 V versus Na/Na+. Na insertion/deinsertion takes place through a solid-solution reaction without a phase separation, which prevents coherent strain or stress in the microstructure during cycling and ensures promising sodium storage properties. These findings demonstrate a great potential of H0.43Ti0.93Nb1.07O5 as the anode, and our strategy can be applied to other layered metal oxides for promising sodium storage properties.
- URI
- https://advances.sciencemag.org/content/3/10/e1700509https://repository.hanyang.ac.kr/handle/20.500.11754/115904
- ISSN
- 2375-2548
- DOI
- 10.1126/sciadv.1700509
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ENERGY ENGINEERING(에너지공학과) > Articles
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