Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
- Title
- Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions
- Author
- 나명수
- Keywords
- ORGANIC FRAMEWORKS; HYDROGEN STORAGE; COUPLING REACTIONS; CATALYSIS; CHEMISTRY; POLYMERIZATION; EFFICIENT; REAGENTS; BROMIDES; LIGAND
- Issue Date
- 2009-07
- Publisher
- AMER CHEMICAL SOC
- Citation
- INORGANIC CHEMISTRY, v. 48, No. 14, Page. 6353-6355
- Abstract
- A new building block containing an imidazolium salt was synthesized and used for the construction of supramolecular networks with metal ions. We discovered the concomitant formation of the N-heterocyclic carbene-copper complex (CN = 2) in the self-assembly of imidazolium dicarboxylates and copper nitrates in N,N-dimethylformamide under heating. The proton in the 2 position of the imidazolium salt was abstracted, and Cu-II was reduced to Cu-I during the self-assembly process.
- URI
- https://pubs.acs.org/doi/abs/10.1021/ic900846shttps://repository.hanyang.ac.kr/handle/20.500.11754/104047
- ISSN
- 0020-1669
- DOI
- 10.1021/ic900846s
- Appears in Collections:
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > ETC
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