Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 나명수 | - |
dc.date.accessioned | 2019-05-13T07:29:37Z | - |
dc.date.available | 2019-05-13T07:29:37Z | - |
dc.date.issued | 2009-07 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v. 48, No. 14, Page. 6353-6355 | en_US |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/ic900846s | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/104047 | - |
dc.description.abstract | A new building block containing an imidazolium salt was synthesized and used for the construction of supramolecular networks with metal ions. We discovered the concomitant formation of the N-heterocyclic carbene-copper complex (CN = 2) in the self-assembly of imidazolium dicarboxylates and copper nitrates in N,N-dimethylformamide under heating. The proton in the 2 position of the imidazolium salt was abstracted, and Cu-II was reduced to Cu-I during the self-assembly process. | en_US |
dc.description.sponsorship | This work was supported by a Korea Research Foundation grant funded by the Korean Government (MOEHRD, Basic Research Promotion Fund; Grant KRF-2008-313-C00455). Dr. I. G. Jung thanks the Hydrogen Energy R&D Center, a 21st century Frontier R&D Program funded by the Ministry of Science and Technology of Korea. The authors acknowledge PAL for beamline use (2008-3063-10). | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | ORGANIC FRAMEWORKS | en_US |
dc.subject | HYDROGEN STORAGE | en_US |
dc.subject | COUPLING REACTIONS | en_US |
dc.subject | CATALYSIS | en_US |
dc.subject | CHEMISTRY | en_US |
dc.subject | POLYMERIZATION | en_US |
dc.subject | EFFICIENT | en_US |
dc.subject | REAGENTS | en_US |
dc.subject | BROMIDES | en_US |
dc.subject | LIGAND | en_US |
dc.title | Concomitant Formation of N-Heterocyclic Carbene-Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/ic900846s | - |
dc.relation.journal | INORGANIC CHEMISTRY | - |
dc.contributor.googleauthor | Chun, Jiseul | - |
dc.contributor.googleauthor | Jung, Il Gu | - |
dc.contributor.googleauthor | Kim, Hae Jin | - |
dc.contributor.googleauthor | Park, Mira | - |
dc.contributor.googleauthor | Lah, Myoung Soo | - |
dc.contributor.googleauthor | Son, Seung Uk | - |
dc.relation.code | 2009204045 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE & TECHNOLOGY[E] | - |
dc.sector.department | DIVISION OF SCIENCE & TECHNOLOGY | - |
dc.identifier.pid | mslah | - |
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