Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 윤소원 | - |
dc.date.accessioned | 2019-08-12T05:18:24Z | - |
dc.date.available | 2019-08-12T05:18:24Z | - |
dc.date.issued | 2019-02 | - |
dc.identifier.citation | ADVANCED SYNTHESIS & CATALYSIS, v. 361, NO 3, Page. 462-468 | en_US |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.issn | 1615-4169 | - |
dc.identifier.uri | https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201801265 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/108475 | - |
dc.description.abstract | A palladium-catalyzed aerobic C-H amidation of N-Ts-2-amino-3 '-hydroxylbiaryls has been developed to afford a diverse range of 1-hydroxycarbazoles with high regioselectivity and efficiency. This protocol benefits from operational simplicity, robustness, and sustainability with the use of ambient air as the sole terminal oxidant. Further elaboration of the products obtained from this process provides facile access to various carbazole alkaloids including carbazolequinones and biscarbazoles. A mechanism involving dual directing group-assisted regioselective C-H activation at the more sterically hindered C2 '-position of 2-amino-3 '-hydroxylbiaryls is proposed. | en_US |
dc.description.sponsorship | This work was supported by both Basic Science Research Program and Nano.Material Technology Department Program through the National Research Foundation of Korea (NRF) funded by the Korea government (MSIP) (Nos. 2012M3A7B4049644, 2014-011165, 2015R1A2A2A01002559, and 2018R1A2A2A05018392). | en_US |
dc.language.iso | en | en_US |
dc.publisher | WILEY-V C H VERLAG GMBH | en_US |
dc.subject | carbazoles | en_US |
dc.subject | C-H activation | en_US |
dc.subject | palladium catalysis | en_US |
dc.subject | regioselectivity | en_US |
dc.title | Palladium-Catalyzed Regioselective Synthesis of 1-Hydroxycarbazoles Under Aerobic Conditions | en_US |
dc.type | Article | en_US |
dc.relation.no | 3 | - |
dc.relation.volume | 361 | - |
dc.identifier.doi | 10.1002/adsc.201801265 | - |
dc.relation.page | 462-468 | - |
dc.relation.journal | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.contributor.googleauthor | Youn, So Won | - |
dc.contributor.googleauthor | Kim, Young Ho | - |
dc.contributor.googleauthor | Jo, Yoon Hyung | - |
dc.relation.code | 2019002950 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | sowony73 | - |
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