Repository at Hanyang UniversityCOLLEGE OF NATURAL SCIENCES[S](자연과학대학)CHEMISTRY(화학과)Articles

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dc.contributor.author조천규-
dc.date.accessioned2018-10-30T00:26:36Z-
dc.date.available2018-10-30T00:26:36Z-
dc.date.issued2016-09-
dc.identifier.citationORGANIC LETTERS, v. 18, NO. 19, Page. 5126-5129en_US
dc.identifier.issn1523-7060-
dc.identifier.issn1523-7052-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/acs.orglett.6b02575-
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/76846-
dc.description.abstractA new synthetic route to (-)-neocosmosin A was devised by elaboration, of intramolecular Diels- Alder (IMDA) cycloaddition of 2-pyrone containing a bromopropiolate group as the dienophile. The IMDA reaction was accompanied by cycloreversion of carbon dioxide to give benzannulated macrolide with two bromide groups at C14 and C16. Installation of the pinacolboryl groups and oxidations allowed completion of the total synthesis of (-)-neocosmosin A.en_US
dc.description.sponsorshipThis work was supported by grants from the National Research Foundation of Korea (2014R1A5A1011165 and 2012M3A7B4049657).en_US
dc.language.isoenen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.subjectRESORCYLIC ACID LACTONESen_US
dc.subjectREGIOSELECTIVE SYNTHESISen_US
dc.subject3,5-DIBROMO-2-PYRONEen_US
dc.subjectBIOSYNTHESISen_US
dc.subjectCHEMISTRYen_US
dc.subject(E)-BETA-BORYLSTYRENEen_US
dc.subjectCYCLOADDITIONSen_US
dc.subjectMACROLACTONESen_US
dc.subject(+/-)-CRININEen_US
dc.subjectNEOCOSMOSINen_US
dc.titleTotal Synthesis of (-)-Neocosmosin A via Intramolecular Diels-Alder Reaction of 2-Pyroneen_US
dc.typeArticleen_US
dc.relation.no19-
dc.relation.volume18-
dc.identifier.doi10.1021/acs.orglett.6b02575-
dc.relation.page5126-5129-
dc.relation.journalORGANIC LETTERS-
dc.contributor.googleauthorLee, Joon-Ho-
dc.contributor.googleauthorCho, Cheon-Gyu-
dc.relation.code2016001127-
dc.sector.campusS-
dc.sector.daehakCOLLEGE OF NATURAL SCIENCES[S]-
dc.sector.departmentDEPARTMENT OF CHEMISTRY-
dc.identifier.pidccho-
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