Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이정호 | - |
dc.date.accessioned | 2018-07-10T06:58:15Z | - |
dc.date.available | 2018-07-10T06:58:15Z | - |
dc.date.issued | 2017-10 | - |
dc.identifier.citation | SOLAR ENERGY MATERIALS AND SOLAR CELLS, v. 171, Page. 267-274 | en_US |
dc.identifier.issn | 0927-0248 | - |
dc.identifier.issn | 1879-3398 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0927024817303744 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/72456 | - |
dc.description.abstract | Earth-abundant, non-toxic, and stable porous Co3O4 film grown by Kirkendall-diffusion is developed for efficient photoelectrocatalytic seawater splitting. Semitransparent Co3O4 films are found highly active hydrogen evolution reaction (HER) photocatalyst with stable performances. Dual band gap (1.5 eV and 2.3 eV) p-type Co3O4 samples exhibiting photo induced HER current density of 25 mA/cm(2) is obtained with overpotential of 0.83 V in the sea-water. Our Co3O4 sample possesses Tafel slope of 20 mV/dec, incident photon to the current conversion efficiency of ˃ 8%, and charge transfer resistance of 3.4 Omega/cm(2). Photo induced Mott-Schottky analysis was applied to find the flat band potential corresponding to the lower band gap value and exhibited strong influence on the majority carrier concentrations and shifting of flat band potential. Electrical properties of Co3O4 material and losses associated in seawater splitting were carefully studied using the Mott-Schottky and electrochemical impedance spectroscopy. Present studies on seawater splitting using Co3O4 not only suggest photoelectrocatalytic hydrogen generation but also usefulness for efficient sea salts formation. | en_US |
dc.description.sponsorship | This research was supported by Basic Science Research Program through the National Research Foundation (NRF) of Korea by the Ministry of Education (NRF-2015R1D1A1A01059165), Korea Research Fellowship Program through the NRF by the Ministry of Science, ICT and Future Planning (NRF-2015H1D3A1066311) and Korea Institute of Energy Technology Evaluation and Planning by the Ministry of Knowledge Economy (KETEP-20168520011370) | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | ELSEVIER SCIENCE BV | en_US |
dc.subject | Co3O4 | en_US |
dc.subject | Kirkendall-diffusion | en_US |
dc.subject | Photoelectrocatalytic | en_US |
dc.subject | Seawater splitting | en_US |
dc.subject | Hydrogen generation | en_US |
dc.title | Photoelectrocatalytic sea water splitting using Kirkendall diffusion grown functional Co3O4 film | en_US |
dc.type | Article | en_US |
dc.relation.volume | 171 | - |
dc.identifier.doi | 10.1016/j.solmat.2017.06.058 | - |
dc.relation.page | 267-274 | - |
dc.relation.journal | SOLAR ENERGY MATERIALS AND SOLAR CELLS | - |
dc.contributor.googleauthor | Patel, Malkeshkumar | - |
dc.contributor.googleauthor | Park, Wang-Hee | - |
dc.contributor.googleauthor | Ray, Abhijit | - |
dc.contributor.googleauthor | Kim, Joondong | - |
dc.contributor.googleauthor | Lee, Jung-Ho | - |
dc.relation.code | 2017001042 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF ENGINEERING SCIENCES[E] | - |
dc.sector.department | DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING | - |
dc.identifier.pid | jungho | - |
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