Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 윤종승 | - |
dc.date.accessioned | 2018-04-26T02:54:54Z | - |
dc.date.available | 2018-04-26T02:54:54Z | - |
dc.date.issued | 2014-02 | - |
dc.identifier.citation | NANO LETTERS, Vol.14 No.2 [2014], 416-422 | en_US |
dc.identifier.issn | 1530-6984 | - |
dc.identifier.issn | 1530-6992 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/nl402747x | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/70722 | - |
dc.description.abstract | For the first time, we report the electrochemical activity of anatase TiO2 nanorods in a Na cell. The anatase TiO2 nanorods were synthesized by a hydrothermal method, and their surfaces were coated by carbon to improve the electric conductivity through carbonization of pitch at 700 °C for 2 h in Ar flow. The resulting structure does not change before and after the carbon coating, as confirmed by X-ray diffraction (XRD). Transmission electron microscopic images confirm the presence of a carbon coating on the anatase TiO2 nanorods. In cell tests, anodes of bare and carbon-coated anatase TiO2 nanorods exhibit stable cycling performance and attain a capacity of about 172 and 193 mAh g–1 on the first charge, respectively, in the voltage range of 3–0 V. With the help of the conductive carbon layers, the carbon-coated anatase TiO2 delivers more capacity at high rates, 104 mAh g–1 at the 10 C-rate (3.3 A g–1), 82 mAh g–1 at the 30 C-rate (10 A g–1), and 53 mAh g–1 at the 100 C-rate (33 A g–1). By contrast, the anode of bare anatase TiO2 nanorods delivers only about 38 mAh g–1 at the 10 C-rate (3.3 A g–1). The excellent cyclability and high-rate capability are the result of a Na+ insertion and extraction reaction into the host structure coupled with Ti4+/3+ redox reaction, as revealed by X-ray absorption spectroscopy. | en_US |
dc.description.sponsorship | This research was partly supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Education, Science and Technology (2011-0024683), the Human Resources Development program (No. 20124010203310) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Trade, Industry, and Energy, and a grant from the National Research Foundation of Korea and funded by the Korean government (MEST) (NRF-2009-C1AAA001-0093307). This work was also supported by the U.S. Department of Energy under Contract DE-AC0206CH11357 with the main support provided by the Vehicle Technologies Office, Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE). J.L. was supported by the Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Postdoctoral Research Award under the EERE. Vehicles Technology Program administered by the Oak Ridge Institute for Science and Education (ORISE) for the DOE. | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA | en_US |
dc.subject | Natase TiO2 | en_US |
dc.subject | nanorods | en_US |
dc.subject | carbon coating | en_US |
dc.subject | intercalation | en_US |
dc.subject | anode | en_US |
dc.subject | sodium battery | en_US |
dc.title | Anatase Titania Nanorods as an Intercalation Anode Material for Rechargeable Sodium Batteries | en_US |
dc.type | Article | en_US |
dc.relation.volume | 14 | - |
dc.identifier.doi | 10.1021/nl402747x | - |
dc.relation.page | 416-422 | - |
dc.relation.journal | NANO LETTERS | - |
dc.contributor.googleauthor | Kim, Ki-Tae | - |
dc.contributor.googleauthor | Ghulam Ali | - |
dc.contributor.googleauthor | Chung, Kyung Yoon | - |
dc.contributor.googleauthor | Yoon, Chong Seung | - |
dc.contributor.googleauthor | Hitoshi Yashiro | - |
dc.contributor.googleauthor | Sun, Yang-Kook | - |
dc.contributor.googleauthor | Lu, Jun | - |
dc.contributor.googleauthor | Khalil Amine | - |
dc.contributor.googleauthor | Myung, Seung-Taek | - |
dc.relation.code | 2014036375 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DIVISION OF MATERIALS SCIENCE AND ENGINEERING | - |
dc.identifier.pid | csyoon | - |
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