Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Justyn Wayne Jaworski | - |
dc.date.accessioned | 2018-04-19T11:50:22Z | - |
dc.date.available | 2018-04-19T11:50:22Z | - |
dc.date.issued | 2013-01 | - |
dc.identifier.citation | Supramolecular chemistry, 2012, 25(1), P.54-59 | en_US |
dc.identifier.issn | 1061-0278 | - |
dc.identifier.uri | https://www.tandfonline.com/doi/abs/10.1080/10610278.2012.721550 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/69818 | - |
dc.description.abstract | The structure of polydiacetylene (PDA) supramolecules offers carboxylic acid-terminated alkyl side-chains around a p conjugated polymer backbone. Exposure of these supramolecules to alkylamines induced disruption of the conjugated PDA backbone via intercalation as revealed by a colorimetric/fluorometric response. This response is demonstrated to be dependent on the length of the alkylamine, offering a new view on intercalation in PDA systems with respect to supramolecules. It is found that this critical carbon chain length of alkylamine required to induce a colour change response must be greater than the alkyl side-chain length of PDA in order to interact with the conjugated backbone. Intercalation of longer species is also found to induce supramolecule aggregation resulting in destabilised PDA suspensions. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Taylor & Francis | en_US |
dc.subject | polydiacetylenes | en_US |
dc.subject | alkylamines | en_US |
dc.subject | intercalation | en_US |
dc.subject | supramolecules | en_US |
dc.subject | sensors | en_US |
dc.title | Size-dependent intercalation of alkylamines within polydiacetylene supramolecules | en_US |
dc.type | Article | en_US |
dc.relation.no | 1 | - |
dc.relation.volume | 25 | - |
dc.identifier.doi | 10.1080/10610278.2012.721550 | - |
dc.relation.page | 54-59 | - |
dc.relation.journal | SUPRAMOLECULAR CHEMISTRY | - |
dc.contributor.googleauthor | Yoon, B. | - |
dc.contributor.googleauthor | Jaworski, J. | - |
dc.contributor.googleauthor | Kim, J.-M. | - |
dc.relation.code | 2013012117 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL ENGINEERING | - |
dc.identifier.pid | justynj | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.