Intramolecular Fischer Indole Synthesis and its Combination with an Aromatic [3,3]-Sigmatropic Rearrangement for the Preparation of Tricyclic Benzo[cd]indoles
- Title
- Intramolecular Fischer Indole Synthesis and its Combination with an Aromatic [3,3]-Sigmatropic Rearrangement for the Preparation of Tricyclic Benzo[cd]indoles
- Author
- 조천규
- Keywords
- aryl hydrazides; benzo[cd]indoles; Fischer indole synthesis; polycycles; sigmatropic rearrangement
- Issue Date
- 2012-01
- Publisher
- Wiley
- Citation
- Angewandte Chemie International Edition, 2012, 51(10), P.2496-2499
- Abstract
- At the end of the tether: Aryl hydrazides that have carbonyl groups tethered at the para position of the aromatic ring undergo an intramolecular Fischer indolization reaction to give the corresponding indolophanes. Strategic insertion of a double bond in the tether enables a tandem aromatic [3,3] sigmatropic rearrangement reaction to occur to give tricyclic benzo[cd]indoles.
- URI
- https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201108970http://hdl.handle.net/20.500.11754/52645
- ISSN
- 1433-7851; 1521-3773
- DOI
- 10.1002/anie.201108970
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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