Cationic Gold-Catalyzed Regioselective Hydration of 1-Arylalkynes through Carbonyl Group Participation
- Title
- Cationic Gold-Catalyzed Regioselective Hydration of 1-Arylalkynes through Carbonyl Group Participation
- Author
- 오창호
- Keywords
- catalysis; regioselectivity; internal alkynes; hydration
- Issue Date
- 2012-04
- Publisher
- GEORG THIEME VERLAG KG
- Citation
- Synlett, 2012, 6, P.897-902
- Abstract
- The unsymmetrically substituted internal alkynes were regioselectively hydrated through carbonyl-group participation using cationic gold catalyst where the nature and position of carbonyl functionalities play a key role in governing the regioselectivity of products as well as facilitating the reaction. A new atom-economical, cationic gold-catalyzed regioselective hydration of 1-arylalkynes substituted with various functionalities in the absence of any toxic catalyst, strong acid, or other additives have been reported.
- URI
- https://www.thieme-connect.de/DOI/DOI?10.1055/s-0031-1290619http://hdl.handle.net/20.500.11754/49712
- ISSN
- 0936-5214
- DOI
- 10.1055/s-0031-1290619
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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