Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 탁정애 | - |
dc.date.accessioned | 2018-03-20T04:56:54Z | - |
dc.date.available | 2018-03-20T04:56:54Z | - |
dc.date.issued | 2014-03 | - |
dc.identifier.citation | Monatshefte fur Chemie, Vol.145 No.7 [2014], pp. 1101-1108 | en_US |
dc.identifier.issn | 0026-9247 | - |
dc.identifier.uri | https://link.springer.com/article/10.1007%2Fs00706-014-1175-z | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11754/49471 | - |
dc.description.abstract | A series of ruthenium(II) complexes containing carboxyvinyl-conjugated phenanthroline and another auxiliary ligand have been designed, synthesized, and characterized. Starting from [RuCl2(p-cymene)](2), two types of Ru(II) complexes, [Ru(dcvphen)(4,7-R-2-phenanthroline)(NCS)(2)] and [Ru(dcvphen)(4,4'-R-2-bipyridine)(NCS)(2)] (dcvphen = 4,7-bis(E-carboxyvinyl)-1,10-phenanthroline, R = -CH = CHCOOH, -COOH, H), were synthesized by a one-pot reaction in DMF. Final products were obtained as a tetrabutylammonium salt form of Ru(II) complexes with reasonable yields. UV-Vis absorption studies on the newly synthesized Ru(II) complexes were carried out. Furthermore, it was shown that a dye-sensitized solar cell fabricated with representative [Ru(dcvphen)(2)(NCS)(2)][TBA](2) complex dye exhibited a reasonable power conversion efficiency of 1.0 %. | en_US |
dc.description.sponsorship | This work is supported by research funds of Hanyang University (HY-2012-G, J. Tak). | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer Science + Business Media | en_US |
dc.subject | Heterocycles | en_US |
dc.subject | Metal complexes | en_US |
dc.subject | Organometallic compounds | en_US |
dc.subject | Photosensitizers | en_US |
dc.subject | Ru(II) complexes | en_US |
dc.title | Synthesis and photophysical properties of new ruthenium(II) charge-transfer sensitizers containing a 4,7-bis(E-carboxyvinyl)-1,10-phenanthroline ligand | en_US |
dc.type | Article | en_US |
dc.relation.volume | 145 | - |
dc.identifier.doi | 10.1007/s00706-014-1175-z | - |
dc.relation.page | 1101-1108 | - |
dc.relation.journal | MONATSHEFTE FUR CHEMIE | - |
dc.contributor.googleauthor | Tak, Jungae | - |
dc.contributor.googleauthor | Kim, Minki | - |
dc.contributor.googleauthor | Park, Sejoo | - |
dc.contributor.googleauthor | Yun, Soo Hong | - |
dc.contributor.googleauthor | Kim, Jihye | - |
dc.contributor.googleauthor | Park, Byoungchoo | - |
dc.contributor.googleauthor | Kim, Byeong Hyo | - |
dc.contributor.googleauthor | 탁정애 | - |
dc.relation.code | 2014036267 | - |
dc.sector.campus | S | - |
dc.sector.daehak | CENTER FOR CREATIVE CONVERGENCE EDUCATION[S] | - |
dc.identifier.pid | jatak | - |
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