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(E)-beta-Borylstyrene in the Diels-Alder Reaction with 3,5-Dibromo-2-pyrone for the Syntheses of (+/-)-1-epi-Pancratistatin and (+/-)- Pancratistatin
- Title
- (E)-beta-Borylstyrene in the Diels-Alder Reaction with 3,5-Dibromo-2-pyrone for the Syntheses of (+/-)-1-epi-Pancratistatin and (+/-)- Pancratistatin
- Other Titles
- -)-1-epi-Pancratistatin and (+
- Author
- 조천규
- Issue Date
- 2013-11
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, 권: 15, 호: 22, 페이지: 5806-5809
- Abstract
- New synthetic routes to (+/-)-1-epi-pancratistatin and (+/-)-pancratistatin were devised using (E)-beta-borylstyrene as a dienophile for the key Diels-Alder reaction with 3,5-dibromo-2-pyrone. The boronate in the cycloadduct was oxidized to provide the pivotal C1-hydroxyl group of the titled compounds.
- ISSN
- 1523-7060; 1523-7052
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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