Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 한양규 | - |
dc.date.accessioned | 2018-02-12T06:25:01Z | - |
dc.date.available | 2018-02-12T06:25:01Z | - |
dc.date.issued | 2011-06 | - |
dc.identifier.citation | Macromolecular research,Macromolecular research,Vol.19,No.6 [2011] ,608-612 | en_US |
dc.identifier.issn | 1598-5032 | - |
dc.identifier.uri | https://link.springer.com/article/10.1007/s13233-011-0616-3 | - |
dc.description.abstract | New poly(arylene ether)s (PAEs) with both transparency and heat-resistance were prepared by the poly-condensation of 4-fluoro-4'(((fluorobenzoyl)phenyl)-oxy)diphenyl sulfone), an ordered-sequence aromatic dihalide, and cardo typed aromatic diols that contain fluorene, adamantane, or cyclohexane moiety. The resulting polymers were found to be amorphous by X-ray diffraction, and their glass transition temperatures ranged from 194 to $245^{\circ}C$. Based on the TGA data, they exhibited excellent thermal stability, showing 5% weight loss at 444-$496^{\circ}C$. They had low thermal expansion coefficients of 58-74 ppm at the temperature range of 50-$200^{\circ}C$ as well as good mechanical properties with moduli of 1,785-2,350 MPa, except for the PAE that contains the cyclohexane moiety (86 ppm at 50-$160^{\circ}C$; 1,070 MPa). The optical transmittance of the PAE films (ca. 40 ${\mu}m$ thick) was more than 70% at 450-800 nm and they also exhibited a very high refractive index in the range of 1.714-1.752 at 589 nm. In addition, their films showed a low water uptake of approximately 0.65% regardless of their chemical composition. Therefore, the newly developed PAEs show strong potential as plastic substrates for flexible devices for displays, solar cells and e-paper. | en_US |
dc.description.sponsorship | This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea. | en_US |
dc.language.iso | en | en_US |
dc.publisher | THE POLYMER SOCIETY OF KOREA | en_US |
dc.subject | cardo based poly(arylene ether)s | en_US |
dc.subject | transparency | en_US |
dc.subject | high heat resistance | en_US |
dc.subject | low coefficient of thermal expansion | en_US |
dc.title | Transparency and high heat resistance of cardo based poly(arylene ether)s for flexible plastic substrates | en_US |
dc.type | Article | en_US |
dc.relation.no | 6 | - |
dc.relation.volume | 19 | - |
dc.identifier.doi | 10.1007/s13233-011-0616-3 | - |
dc.relation.page | 608-612 | - |
dc.relation.journal | MACROMOLECULAR RESEARCH | - |
dc.contributor.googleauthor | Kong, Gyoung-Pyo | - |
dc.contributor.googleauthor | Hong, Bo-Ra | - |
dc.contributor.googleauthor | Kim, Moon-Ki | - |
dc.contributor.googleauthor | Han, Yang-Kyoo | - |
dc.contributor.googleauthor | Chun, Hyun-Aee | - |
dc.relation.code | 2011210429 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | ykhan | - |
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