Synthesis and photophysical properties of silicon(IV) tetrapyrazinoporphyrazines axially substituted with ethylene glycol chains as potential photosensitizer
- Title
- Synthesis and photophysical properties of silicon(IV) tetrapyrazinoporphyrazines axially substituted with ethylene glycol chains as potential photosensitizer
- Author
- 정재윤
- Keywords
- ethylene glycol chain; silicon tetrapyrazinoporphyrazine; singlet oxygen; aggregation
- Issue Date
- 2015-08
- Publisher
- WORLD SCI PUBL CO INC
- Citation
- JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, v. 19, NO 8, Page. 967-972
- Abstract
- Photodynamic therapy involves administration of a tumor-localizing photosensitizer, which may require metabolic conversion, followed by activation of the photosensitizer with light of a specific wavelength. In this paper, we report the design and synthesis of silicon(IV) tetrapyrazinoporphyrazines derived from 5,9,9-trimethyl-5,6,7,8-tetrahydro-5,8-methanoquinoxaline-2,3-dicarbonitrile. The HO-(CH2CH2O)(n)-CH3 groups were introduced at axial positions to give a specific functionality. In particular, poly(ethylene glycol) groups were expected to increase water solubility without changing the lambda(max).
- URI
- http://www.worldscientific.com/doi/abs/10.1142/S1088424615500698http://hdl.handle.net/20.500.11754/27028
- ISSN
- 1088-4246; 1099-1409
- DOI
- 10.1142/S1088424615500698
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ORGANIC AND NANO ENGINEERING(유기나노공학과) > Articles
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