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dc.contributor.advisor김진국-
dc.contributor.author원아연-
dc.date.accessioned2024-03-01T07:32:37Z-
dc.date.available2024-03-01T07:32:37Z-
dc.date.issued2023.2-
dc.identifier.urihttp://hanyang.dcollection.net/common/orgView/200000651270en_US
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/188225-
dc.description.abstractThegoalofreachingnetzeroby2050hasbeenestablishedtoaddressexistingenvironmentalconcerns.Hydrogenisanticipatedtoplayakeyroleinachievingtheenergytransitionsinceitcanbeutilizedasvarioustypesoffuelstogeneratedifferentkindsofenergy.Itismainlyproducedbysteammethanereforming(SMR)technologyusingnaturalgasinthepresent,althoughthisusesalotofsteamandthermalenergy,bothofwhichhaveahighCO2cost. Todevelopenvironmentallyadvancedhydrogenproductionprocesses,otherreactions,includingauto-thermalreforming(ATR)andpartialoxidation(POX),havebeensuggestedinthisresearch.Additionally,electricheatersreplacedtheconventionalfurnacesintheSMRandATRprocesses,andtheOrganicRankineCycle(ORC)convertedleftoverheattoelectricity.Finally,thecarboncaptureunithasbeenintegratedintoeachprocessforthesakeofcarbonreduction.TheprocessesaredescribedinthereportbyIEAGHGandsimulatedthroughAspenHYSYS®.Then,theenvironmentaleffectswerequantifiedfromprocessdatausingSimaPro®aspartofthelife-cycleassessmentprocess,specificallytheglobalwarmingpotential(GWP).TheassessmentsfollowedIPCC2013GWP100amethodwithEcoinvent3database. TheSMRprocesshada77.6%largeremissionwithane-furnacethanthebasecasebecausethereactorisincapableofburningallthemethanebyitselfandtheoff-gaswasassumedtobereleaseddirectlytotheair.Eventhecarboncapturecannotdroptill10.44GWPofthebasescenariosincetheCH4accountingratiowasfartoohigh.So,itneededanadditionalfurnaceafterthePSAunit,whichcandecreasetheemissionto2.62GWPand-1.51GWPwiththecarboncapture.Otherwise,ATRreactorcanutilizethemethaneforcombustionreactions,resultingin11.01GWP,whichisalowervaluethantheSMRelectrificationcaseandtheATRbasecase.Also,mostoftheemissionwasconsistofCO2,whichcanbecapturedbytheunit,sothattheelectrificationandcarboncapturecasehadarelativelylowemissionof4.66kg.Lastly,POXhasbenefitedfromtheprocessrenovation,asithastheabilitytodirectlyburnmethaneinthereactor.Itimpliesthattheoff-gasdidnotcontainCH4andthattheCO2wascapturedbythemonoethanolamine(MEA).TheprocesswiththeORCsystemhad11.03GWP,whichis0.29lowerthanthebasecase,andthecarboncapturereduceditsvalueto2.55GWP.Inconclusion,theSMRprocesswithanelectricheateristheworstoption,sothatitneedsanadditionalburner.ThePOXprocesswithORCandcarboncaptureisoneoftheenvironment-friendlyscenarios,evenwithoutafurnace.-
dc.publisher한양대학교-
dc.titleSustainableProcessDesignandLife-cycleAssessment(LCA)ofHydrogenProductionusingNaturalGas-
dc.title.alternative천연가스를이용한수소생산기술의지속가능한공정설계와전과정환경성평가-
dc.typeTheses-
dc.contributor.googleauthor원아연-
dc.contributor.alternativeauthorAhyeonWon-
dc.sector.campusS-
dc.sector.daehak대학원-
dc.sector.department화학공학과-
dc.description.degreeMaster-
dc.contributor.affiliation공정설계-
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GRADUATE SCHOOL[S](대학원) > CHEMICAL ENGINEERING(화학공학과) > Theses (Master)
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