Angewandte Chemie - International Edition, v. 45, NO. 6, Page. 916-920
Abstract
A handy approach: A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal-organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. (Figure Presented).