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Oxidative rearrangement of ketimines to amides by MCPBA and BF3-OEt2

Title
Oxidative rearrangement of ketimines to amides by MCPBA and BF3-OEt2
Author
이학준
Keywords
oxidative rearrangement; ketimines; ketones; migratory aptitude; amides
Issue Date
2003-01
Publisher
Georg Thieme Verlag
Citation
Synlett, NO. 1, Page. 112-114
Abstract
Several amides were obtained by an efficient method from the corresponding alkyl aryl ketimines in high yields. Ketimines are readily prepared from the corresponding ketones. This procedure involves the oxidation of alkyl aryl ketimines with MCPBA with BF3.OEt2. In this reaction, only aryl group of alkyl aryl ketimines was migrated to the electron deficient nitrogen atom.
URI
https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-2003-36240https://repository.hanyang.ac.kr/handle/20.500.11754/184005
ISSN
0936-5214;1437-2096
DOI
10.1055/s-2003-36240
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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