Pd nanoparticles immobilized on PNIPAMhalloysite: highly active and reusable catalyst for Suzuki-Miyaura coupling reactions in water
- Title
- Pd nanoparticles immobilized on PNIPAMhalloysite: highly active and reusable catalyst for Suzuki-Miyaura coupling reactions in water
- Author
- 이학준
- Keywords
- Suzuki-Miyaura reactions; Pd nanoparticles; PNIPAM-halloysite nanocomposite; reusable catalysts; water
- Issue Date
- 2014-03
- Publisher
- John Wiley & Sons Inc.
- Citation
- Applied Organometallic Chemistry, v. 28, NO. 3, Page. 156-161
- Abstract
- Poly(N-isopropylacrylamide)-halloysite (PNIPAM-HNT) nanocomposites exhibited inverse temperature solubility with a lower critical solution temperature (LCST) in water. Palladium (Pd) nanoparticles were anchored on PNIPAM-HNT nanocomposites with various amounts of HNT from 5 to 30wt%. These Pd catalysts exhibited excellent reactivities for Suzuki-Miyaura coupling reactions at 50-70 degrees C in water. In particular, Pd anchored PNIPAM/HNT (95:5 w/w ratio) nanocomposites showed excellent recyclability up to 10 times in 96% average yield by simple filtration. Copyright (c) 2014 John Wiley & Sons, Ltd.
- URI
- https://onlinelibrary.wiley.com/doi/10.1002/aoc.3103https://repository.hanyang.ac.kr/handle/20.500.11754/183973
- ISSN
- 0268-2605;1099-0739
- DOI
- 10.1002/aoc.3103
- Appears in Collections:
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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