138 0

Pd nanoparticles immobilized on PNIPAMhalloysite: highly active and reusable catalyst for Suzuki-Miyaura coupling reactions in water

Title
Pd nanoparticles immobilized on PNIPAMhalloysite: highly active and reusable catalyst for Suzuki-Miyaura coupling reactions in water
Author
이학준
Keywords
Suzuki-Miyaura reactions; Pd nanoparticles; PNIPAM-halloysite nanocomposite; reusable catalysts; water
Issue Date
2014-03
Publisher
John Wiley & Sons Inc.
Citation
Applied Organometallic Chemistry, v. 28, NO. 3, Page. 156-161
Abstract
Poly(N-isopropylacrylamide)-halloysite (PNIPAM-HNT) nanocomposites exhibited inverse temperature solubility with a lower critical solution temperature (LCST) in water. Palladium (Pd) nanoparticles were anchored on PNIPAM-HNT nanocomposites with various amounts of HNT from 5 to 30wt%. These Pd catalysts exhibited excellent reactivities for Suzuki-Miyaura coupling reactions at 50-70 degrees C in water. In particular, Pd anchored PNIPAM/HNT (95:5 w/w ratio) nanocomposites showed excellent recyclability up to 10 times in 96% average yield by simple filtration. Copyright (c) 2014 John Wiley & Sons, Ltd.
URI
https://onlinelibrary.wiley.com/doi/10.1002/aoc.3103https://repository.hanyang.ac.kr/handle/20.500.11754/183973
ISSN
0268-2605;1099-0739
DOI
10.1002/aoc.3103
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE