Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유효종 | - |
dc.date.accessioned | 2021-07-27T01:19:16Z | - |
dc.date.available | 2021-07-27T01:19:16Z | - |
dc.date.issued | 2020-02 | - |
dc.identifier.citation | INORGANIC CHEMISTRY FRONTIERS, v. 7, no. 4, page. 905-910 | en_US |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2020/QI/C9QI01381D#!divAbstract | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/163160 | - |
dc.description.abstract | The effective incorporation of well-defined coordination spheres, multiple types of ligands (heteroleptic), and specific assembly modes in a given structure enables the fabrication of simplified coordinative supramolecular bio-mimics. Herein, we report the fabrication of a unique racemic macrocycle via association of metallosupramolecular helicates. A nickel ({Ni-4}) cluster-based supramolecular helicate, [Ni-8(PDA)(6)(CDBA)(3)(DMF)(2)(H2O)(4)] (1) (PDA = 2,6-pyridinedicarboxylate, CDBA = 4,4 '-carbonyldibenzoate, DMF = dimethylformamide), is successfully synthesized and fully characterized. Dimerization of right (P-) and left (M-) handed helicates of 1via the coordination of metalloligands, [Ni(PDA(2))](2-) affords {[Ni-8(PDA)(6)(CDBA)(3)(DMF)(4)-Ni(PDA)(2)](2)} (2), which can be a representative model of the coordinative helix-helix association of heteroleptic helicates. The solid-state structures of 1 and 2 show high and selective CO2 uptake properties. | en_US |
dc.description.sponsorship | This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government Ministry of Science and ICT (MSICT) (NRF-2015R1A4A1041631, NRF-2016R1A2B4009281, and NRF-2018R1A6A3A01013041). Experiments at PLS-II were supported in part by MSICT and POSTECH (2019-1st-2D-009 and 2019-2nd-2D-015). Magnetic measurements were performed using facilities at IBS Center for Correlated Electron Systems, Seoul National University. This research was also supported by the Korea Basic Science Institute under the R&D program (Project No. D39701) supervised by the Ministry of Science and ICT. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.title | Coordinative helix-helix association of heteroleptic metallosupramolecular helicates | en_US |
dc.type | Article | en_US |
dc.relation.no | 4 | - |
dc.relation.volume | 7 | - |
dc.identifier.doi | 10.1039/c9qi01381d | - |
dc.relation.page | 905-910 | - |
dc.relation.journal | INORGANIC CHEMISTRY FRONTIERS | - |
dc.contributor.googleauthor | Kang, P. | - |
dc.contributor.googleauthor | Yoo, H. | - |
dc.relation.code | 2020046714 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF ENGINEERING SCIENCES[E] | - |
dc.sector.department | DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING | - |
dc.identifier.pid | hjhaha73 | - |
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