A three-dimensional helical coordination network of hexanuclear manganese metallamacrocycle as a helical tecton
- Title
- A three-dimensional helical coordination network of hexanuclear manganese metallamacrocycle as a helical tecton
- Author
- 나명수
- Issue Date
- 2004-12
- Publisher
- AMER CHEMICAL SOC
- Citation
- Inorganic Chemistry.v.43, No.26, Page.8230-8232
- Abstract
- We report on helical coordination networks that were prepared using a hexanuclear manganese metallamacrocycle as a helical tecton. We were able to prepare the three-dimensional helical coordination networks using a hexanuclear manganese metallamacrocycle, [Mn-6(IshZ)(6)], as a helical tecton, where N-lauroyl salicylhydrazide (H(3)Ishz) was used as the primary building unit to generate the helical tecton as a secondary building unit. While the 4(1)/4(3) screw symmetry-linked helical coordination network was obtained when the primary building units had an N-acetyl group, both the 3(1)/3(2) screw symmetry-linked and the 4(1)/4(3) screw symmetry-linked helical coordination networks were obtained simultaneously in the same batch when the primary building unit had a long alkyl N-lauroyl group at the N-acetyl site.
- URI
- https://pubs.acs.org/doi/10.1021/ic049393jhttps://repository.hanyang.ac.kr/handle/20.500.11754/154147
- ISSN
- 00201669
- DOI
- 10.1021/ic049393
- Appears in Collections:
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > ETC
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