High Performance Electrochemical Capacitor Using Redox-Active Organic Molecule Coupled with Irreversible Chemical Process
- Title
- High Performance Electrochemical Capacitor Using Redox-Active Organic Molecule Coupled with Irreversible Chemical Process
- Other Titles
- 화학 반응으로 인한 비가역적 산화 환원 반응의 유기분자를 사용한 고성능 전기 화학 커패시터
- Author
- 전재현
- Alternative Author(s)
- 전재현
- Advisor(s)
- 장진호
- Issue Date
- 2020-08
- Publisher
- 한양대학교
- Degree
- Master
- Abstract
- Redox-enhanced electrochemical capacitors (Redox-ECs), in which
electrons are stored and released by redox reactions of organic molecules
either dissolved in an electrolyte or adsorbed on an electrode surface,
represent a promising energy storage system with electrochemical
characteristics of both rechargeable batteries and electrical double-layer
capacitors. However, the choices for redox-active organic molecules in
Redox-ECs are often limited due to an irreversible nature induced by
chemical processes, such as hydrolysis, coupled with etransfer
reactions.
Here, this thesis describes the effects of nano-confinement on enhanced
reversibility in the redox reaction of an electro-active organic molecule
undergoing irreversible hydrolysis after etransfers
in a nanoporous
carbon electrode. The redox reaction between hydrated Rhdizonic acid
(RDZ·2H2O) and Hexahydroxybenzene (HHB) via Tetrahydroxy-1,4-
benzoquinone served as a model in which RDZ is irreversibly hydrolyzed to
RDZ·2H2O. Due to the enhanced reversibility of the RDZ·2H2O/HHB redox
reaction in a nanoporous carbon electrode, Coulombic efficiency of the cell ix
remained near 90% despite the irreversible nature of RDZ via hydrolysis.
This thesis provides fundamental insights into new opportunities to use
organic molecules in energy storage using redox electrolytes such as Redox
ECs and organic redox flow batteries.
- URI
- https://repository.hanyang.ac.kr/handle/20.500.11754/152816http://hanyang.dcollection.net/common/orgView/200000438160
- Appears in Collections:
- GRADUATE SCHOOL[S](대학원) > CHEMISTRY(화학과) > Theses (Master)
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