물리적 파쇄법을 통해 합성된 리튬공기전지용 고효율 산화코발트-그라파이트 복합체의 전기화학적 특성에 대한 연구

Abstract

A new physical pulverization strategy has been developed to prepare a highly active composite of CoOx and crushed graphite (CG) for the cathode in lithium-oxygen batteries. The effect of CoOx loading on the charge potential in the oxygen evolution reaction (Li2O2 → 2Li+ + O2 + 2e-) was investigated in coincell tests. The CoOx (38.9 wt%)/CG composite showed a low charge potential of 3.92 V with a delivered capacity of 2 mAhcm-2 under a current density of 0.2 mAcm-2. The charge potential was 4.10 and 4.15 V at a capacity of 5 and 10 mAhcm-2, respectively, with a current density of 0.5 mAcm-2. The stability of the electrolyte and discharge product on the gas-diffusion layer after the cycling were preliminarily characterized by 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. The high activity of the composite was further analyzed by electrochemical impedance spectroscopy, cyclic voltammetry, and potential-step chronoamperometry. The reults indicate that our near-dry milling method is an effective and green approach to preparing a nanocomposite cathode with high surface area and porosity, while using less solvent. Its relative simplicity compared with the traditional solution method could facilitate its widespread application in catalysis, energy storage, and materials science.