Specific capacitance-pore texture relationship of biogas slurry mesoporous carbon/MnO2 composite electrodes for supercapacitors
- Title
- Specific capacitance-pore texture relationship of biogas slurry mesoporous carbon/MnO2 composite electrodes for supercapacitors
- Author
- 김희택
- Keywords
- Biogas slurry; Mesoporous carbon; Manganese oxide; Supercapacitors; Specific capacitance and composites
- Issue Date
- 2019-02
- Publisher
- Elsevier BV
- Citation
- Nano-Structures and Nano-Objects, v. 17, Page. 21-33
- Abstract
- Here, we report synthesis of biogas slurry mesoporous carbon/MnO
2
composites by simple co-precipitation route followed by thermal treatment at 250 °C for 6 h. The texture, morphology, crystal structure, and microstructure of the composites are investigated by nitrogen sorption studies, FESEM, HRTEM, X-ray diffraction, and Raman spectroscopy. All samples exhibit type IV isotherms. The BET surface area decreased from 514 to 110 m2 g
−1
while total pore volume decreased from 0.52 to 0.17 cm
3
g
−1
for samples loaded with
2×10−5
and
2×10−3
moles of Mn. The electrodes fabricated exhibit high specific capacitance of 709 F g−1 at scan rate of 5 mV s−1. The specific capacitance at scan rate of 5 mV s−1 increases with increasing MnO2 content. However, at 50 mV s−1, specific capacitance decreases with increasing MnO2 content. Varying the MnO2 content and hence the textural parameters, strongly influences the specific capacitances of the composite electrodes.
- URI
- https://www.sciencedirect.com/science/article/pii/S2352507X18302397https://repository.hanyang.ac.kr/handle/20.500.11754/121722
- ISSN
- 2352-507X
- DOI
- 10.1016/j.nanoso.2018.10.002
- Appears in Collections:
- COLLEGE OF ENGINEERING SCIENCES[E](공학대학) > MATERIALS SCIENCE AND CHEMICAL ENGINEERING(재료화학공학과) > Articles
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