Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 오창호 | - |
dc.date.accessioned | 2019-12-09T02:16:59Z | - |
dc.date.available | 2019-12-09T02:16:59Z | - |
dc.date.issued | 2018-09 | - |
dc.identifier.citation | NEW JOURNAL OF CHEMISTRY, v. 42, no. 20, page. 16886-16890 | en_US |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.issn | 1369-9261 | - |
dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2018/NJ/C8NJ03955K#!divAbstract | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/120006 | - |
dc.description.abstract | A simple, mild, efficient and chemoselective catalytic method for the straightforward synthesis of an interesting class of 2-aryl/alkyl-substituted-3-diaryl indolyl methanes in high yield is reported. This atom-efficient method proceeds via a gold-catalyzed one-pot sequential intramolecular hydroamination (C-N bond formation) of 2-alkynylanilines followed by a 1,6-conjugate addition to p-quinonemethides. The p-quinonemethides, which contain aldehyde functional groups, preferentially participate in 1,6-conjugate addition, while the aldehyde functional group remains unreactive. | en_US |
dc.description.sponsorship | This work was supported by a grant from the National Research Foundation of Korea (NRF), funded by the Korean Government, through the Center for New Directions in Organic Synthesis (NRF-2014R1A5A1011165). | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | ROYAL SOC CHEMISTRY | en_US |
dc.subject | CROSS-COUPLING REACTIONS | en_US |
dc.subject | ELECTROPHILIC CYCLIZATION | en_US |
dc.subject | SEQUENTIAL ARYLATION | en_US |
dc.subject | O-ALKYNYLANILINES | en_US |
dc.subject | TRIARYLMETHANES | en_US |
dc.subject | INDOLES | en_US |
dc.subject | DERIVATIVES | en_US |
dc.subject | ALDEHYDES | en_US |
dc.subject | AGENTS | en_US |
dc.subject | BIS(INDOLYL)METHANES | en_US |
dc.title | Gold-catalyzed tandem reaction of 2-alkynylanilines followed by 1,6-conjugate addition to p-quinone methides: efficient access to unsymmetrical diarylindolylmethanes | en_US |
dc.type | Article | en_US |
dc.relation.no | 20 | - |
dc.relation.volume | 42 | - |
dc.identifier.doi | 10.1039/c8nj03955k | - |
dc.relation.page | 16886-16890 | - |
dc.relation.journal | NEW JOURNAL OF CHEMISTRY | - |
dc.contributor.googleauthor | Jillella, Raveendra | - |
dc.contributor.googleauthor | Oh, Dong Hwan | - |
dc.contributor.googleauthor | Oh, Chang Ho | - |
dc.relation.code | 2018002452 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | changho | - |
dc.identifier.researcherID | M-6652-2018 | - |
dc.identifier.orcid | http://orcid.org/0000-0002-7208-4261 | - |
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