Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김동원 | - |
dc.date.accessioned | 2019-12-02T19:58:21Z | - |
dc.date.available | 2019-12-02T19:58:21Z | - |
dc.date.issued | 2017-12 | - |
dc.identifier.citation | SCIENTIFIC REPORTS, v. 7, Article no. 17482 | en_US |
dc.identifier.issn | 2045-2322 | - |
dc.identifier.uri | https://www.nature.com/articles/s41598-017-17697-0 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/116472 | - |
dc.description.abstract | Amorphous poly(ethylene ether carbonate) (PEEC), which is a copolymer of ethylene oxide and ethylene carbonate, was synthesized by ring-opening polymerization of ethylene carbonate. This route overcame the common issue of low conductivity of poly(ethylene oxide)(PEO)-based solid polymer electrolytes at low temperatures, and thus the solid polymer electrolyte could be successfully employed at the room temperature. Introducing the ethylene carbonate units into PEEC improved the ionic conductivity, electrochemical stability and lithium transference number compared with PEO. A cross-linked solid polymer electrolyte was synthesized by photo cross-linking reaction using PEEC and tetraethyleneglycol diacrylate as a cross-linking agent, in the form of a flexible thin film. The solidstate Li/LiNi0.6Co0.2Mn0.2O2 cell assembled with solid polymer electrolyte based on cross-linked PEEC delivered a high initial discharge capacity of 141.4 mAh g(-1) and exhibited good capacity retention at room temperature. These results demonstrate the feasibility of using this solid polymer electrolyte in all-solid-state lithium batteries that can operate at ambient temperatures. | en_US |
dc.description.sponsorship | This work was supported by Samsung SDI and the R&D Convergence Program of the NST (National Research Council of Science & Technology) of the Republic of Korea. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | NATURE PUBLISHING GROUP | en_US |
dc.subject | CO-ETHYLENE CARBONATE) | en_US |
dc.subject | LI-ION CONDUCTORS | en_US |
dc.subject | DIELECTRIC-RELAXATION | en_US |
dc.subject | OXIDE | en_US |
dc.subject | COMPLEXES | en_US |
dc.subject | CONDUCTIVITY | en_US |
dc.subject | CELLS | en_US |
dc.title | Room-Temperature Performance of Poly(Ethylene Ether Carbonate)-Based Solid Polymer Electrolytes for All-Solid-State Lithium Batteries | en_US |
dc.type | Article | en_US |
dc.relation.volume | 7 | - |
dc.identifier.doi | 10.1038/s41598-017-17697-0 | - |
dc.relation.page | 1-11 | - |
dc.relation.journal | SCIENTIFIC REPORTS | - |
dc.contributor.googleauthor | Jung, Yun-Chae | - |
dc.contributor.googleauthor | Park, Myung-Soo | - |
dc.contributor.googleauthor | Kim, Duck-Hyun | - |
dc.contributor.googleauthor | Ue, Makoto | - |
dc.contributor.googleauthor | Eftekhari, Ali | - |
dc.contributor.googleauthor | Kim, Dong-Won | - |
dc.relation.code | 2017003408 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL ENGINEERING | - |
dc.identifier.pid | dongwonkim | - |
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