Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 선양국 | - |
dc.date.accessioned | 2019-11-20T10:40:19Z | - |
dc.date.available | 2019-11-20T10:40:19Z | - |
dc.date.issued | 2017-02 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, v. 29, no. 4, page. 1684-1694 | en_US |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.issn | 1520-5002 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.chemmater.6b05092 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/112731 | - |
dc.description.abstract | Rechargeable zinc-ion batteries (ZIBs) with high energy densities appear promising to meet the increasing demand for safe and sustainable energy storage devices. 1.5 However, electrode research on this low-cost and green system are faced with stiff challenges of identifying materials that permit divalent ion-intercalation/deintercalation. Herein, we present layered-type LiV3O8 (LVO) as a prospective intercalation cathode for zinc-ion batteries (ZIBs) with high storage capacities. The detailed phase evolution study during Zn intercalation using electrochemistry, in situ XRD, and simulation techniques reveals the large presence of a single-phase domain that proceeds via a stoichiometric ZnLiV3O8 phase to reversible solid-solution ZnyLiV3O8 (y > 1) phase. The unique behavior, which is different from the reaction with lithium, contributes to high specific capacities of 172 mAh g(-1) and amounts to 75% retention of the maximum capacity achieved in 65 cycles with 100% Coulombic efficiency at a current density of 133 mA g(-1). The remarkable performance makes the development of this low-cost and safe battery technology very promising, and this study also offers opportunities to enhance the understanding on electrochemically induced metastable phases for energy storage applications. | en_US |
dc.description.sponsorship | This work was supported by the Global Frontier Program through the Global Frontier Hybrid Interface Materials (GFHIM) of the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (2013M3A6B1078875 or 2013-073298). This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (2014R1A2A1A100.50821). | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | PERFORMANCE | en_US |
dc.subject | INSERTION | en_US |
dc.subject | CRYSTAL | en_US |
dc.subject | ELECTRODES | en_US |
dc.subject | TRANSITION | en_US |
dc.subject | CHALLENGES | en_US |
dc.subject | LI1+XV3O8 | en_US |
dc.subject | CHEMISTRY | en_US |
dc.subject | MECHANISM | en_US |
dc.subject | BETA-MNO2 | en_US |
dc.title | Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode | en_US |
dc.type | Article | en_US |
dc.relation.no | 4 | - |
dc.relation.volume | 29 | - |
dc.identifier.doi | 10.1021/acs.chemmater.6b05092 | - |
dc.relation.page | 1684-1694 | - |
dc.relation.journal | CHEMISTRY OF MATERIALS | - |
dc.contributor.googleauthor | Alfaruqi, Muhammad H. | - |
dc.contributor.googleauthor | Mathew, Vinod | - |
dc.contributor.googleauthor | Song, Jinju | - |
dc.contributor.googleauthor | Kim, Sungjin | - |
dc.contributor.googleauthor | Islam, Saiful | - |
dc.contributor.googleauthor | Pham, Duong Tung | - |
dc.contributor.googleauthor | Jo, Jeonggeun | - |
dc.contributor.googleauthor | Kim, Seokhun | - |
dc.contributor.googleauthor | Baboo, Joseph Paul | - |
dc.contributor.googleauthor | Sun, Yang-Kook | - |
dc.relation.code | 2017001951 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF ENERGY ENGINEERING | - |
dc.identifier.pid | yksun | - |
dc.identifier.researcherID | B-9157-2013 | - |
dc.identifier.orcid | http://orcid.org/0000-0002-0117-0170 | - |
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