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Au(I)-catalyzed intramolecular oxidative cyclopropanation of 1,6-enynes derived from propiolamides with diphenyl sulfoxide

Title
Au(I)-catalyzed intramolecular oxidative cyclopropanation of 1,6-enynes derived from propiolamides with diphenyl sulfoxide
Author
신승훈
Keywords
CONTAINING NATURAL-PRODUCTS; IN-SITU GENERATION; INTERMOLECULAR REACTIONS; GOLD; ALKYNES; REARRANGEMENT; ALKENES; YLIDES; CYCLOISOMERIZATION; VINYLDIAZOMETHANES
Issue Date
2013-01
Publisher
Royal Society Chemistry
Citation
ChemInform, 2013, 44(27), 1089-1092
Abstract
We have developed gold(I)-catalyzed oxidative cyclopropanation of 1,6-enynes derived from propiolamides employing diphenyl sulfoxide as an oxidant. 1,6-Enynes having a terminal alkyne and a propiolamide tether efficiently transformed into cyclopropane carboxaldehyde derivatives.
URI
http://pubs.rsc.org/-/content/articlelanding/2013/ob/c2ob27394b/unauth#!divAbstracthttps://repository.hanyang.ac.kr/handle/20.500.11754/69665
ISSN
1477-0520
DOI
10.1039/C2OB27394B
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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