Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 조천규 | - |
dc.date.accessioned | 2018-04-13T09:41:32Z | - |
dc.date.available | 2018-04-13T09:41:32Z | - |
dc.date.issued | 2011-12 | - |
dc.identifier.citation | Organic Letters, 2011, 13(21), 5890p ~ 5892p | en_US |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/ol202525a | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11754/65899 | - |
dc.description.abstract | A new synthetic route to (±)-pancratistatin was devised utilizing β-silyl styrene as a dienophile in the cycloaddition with 3,5-dibromo-2-pyrone. The TMS group incorporated in the cycloadduct permitted a facile elimination process for the eventual installation of the C(1)–OH function. Subsequent transformations including Curtius rearrangement and Bischler–Napieralski reactions completed the total synthesis of (±)-pancratistatin. | en_US |
dc.language.iso | en | en_US |
dc.publisher | THE AMERICAN CHEMICAL SOCIETY | en_US |
dc.subject | Amaryllidaceae Alkaloids | en_US |
dc.subject | chemical synthesis | en_US |
dc.subject | Cyclization, Isoquinolines | en_US |
dc.subject | Molecular Structure | en_US |
dc.subject | Pyrones, chemistry | en_US |
dc.subject | Silicon, Styrene | en_US |
dc.title | beta-Silyl Styrene As a Dienophile in the Cycloaddition with 3,5-Dibromo-2-pyrone for the Total Synthesis of (+/-)-Pancratistatin | en_US |
dc.title.alternative | -)-Pancratistatin | en_US |
dc.type | Article | en_US |
dc.relation.no | 21 | - |
dc.relation.volume | 13 | - |
dc.identifier.doi | 10.1021/ol202525a | - |
dc.relation.page | 5890-5892 | - |
dc.relation.journal | ORGANIC LETTERS | - |
dc.contributor.googleauthor | Jung, Y.-G | - |
dc.contributor.googleauthor | Kang, H.-U. | - |
dc.contributor.googleauthor | Cho, H.-K | - |
dc.contributor.googleauthor | Cho, C.-G. | - |
dc.relation.code | 2011207322 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | ccho | - |
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