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Aerobic oxygenative cleavage of electron deficient C-C triple bonds in the gold-catalyzed cyclization of 1,6-enynes
- Title
- Aerobic oxygenative cleavage of electron deficient C-C triple bonds in the gold-catalyzed cyclization of 1,6-enynes
- Author
- 신승훈
- Keywords
- CYCLOADDITION REACTIONS; MOLECULAR-OXYGEN; OXIDATION; CYCLOISOMERIZATIONS; DIOXYGEN; CYCLOBUTENES; (Z)-ENYNOLS; ATMOSPHERE; PHOTOREDOX; MECHANISM
- Issue Date
- 2014-08
- Publisher
- ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
- Citation
- Chemical Communications (Cambridge, England), 2014, 50(84), p.12722 ~ 12727
- Abstract
- Gold-catalyzed aerobic oxygenative cleavage of triple bonds that occurs under the ambient pressure of air and at room temperature is reported; radical inhibition tests suggest that oxygenation occurs via a gold-bound metalloradical intermediate.
- URI
- http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC04153D#!divAbstracthttp://hdl.handle.net/20.500.11754/48099
- ISSN
- 1359-7345
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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