Entry to beta-Alkoxyacrylates via Gold-Catalyzed Intermolecular Coupling of Alkynoates and Allylic Ethers
- Title
- Entry to beta-Alkoxyacrylates via Gold-Catalyzed Intermolecular Coupling of Alkynoates and Allylic Ethers
- Author
- 신승훈
- Keywords
- CLAISEN-TYPE REARRANGEMENT; INTRAMOLECULAR CARBOALKOXYLATION; GOLD(I)-CATALYZED SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; ALKYNES; ALKENES; CYCLIZATION; COMPLEXES; LIGAND; CYCLOISOMERIZATION
- Issue Date
- 2013-02
- Publisher
- THE AMERICAN CHEMICAL SOCIETY
- Citation
- ORGANIC LETTERS, Feb 2013, 15(6), P.1166-1249
- Abstract
- The first gold-catalyzed Intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted beta-alkoxyacrylates in a highly efficient manner.
- URI
- http://pubs.acs.org/doi/10.1021/ol4001087http://hdl.handle.net/20.500.11754/43958
- ISSN
- 1523-7060
- DOI
- 10.1021/ol4001087
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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