Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이영무 | - |
dc.date.accessioned | 2018-02-14T04:42:17Z | - |
dc.date.available | 2018-02-14T04:42:17Z | - |
dc.date.issued | 2011-09 | - |
dc.identifier.citation | MACROMOLECULES, Vol.44, No.18 [2011], p7296-7306 | en_US |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/ma2015968 | - |
dc.description.abstract | A new bisphenol monomer, 9,9-bis(3,5-dimethoxy-4-hydroxyphenyl) fluorene, was synthesized and polymerized to form fluorene-based poly(arylene ether sulfone) copolymers containing tetra-methoxy groups (MPAES). After converting the methoxy group to the reactive hydroxyl group, the respective side-chain type sulfonated copolymers (SPAES) were obtained by sulfobutylation. The polymers were characterized by (1)H NMR, thermogravimetric analysis (TGA), water uptake, and proton and methanol transport for fuel cell applications. These SPAES copolymers had good overall properties as polymer electrolyte membrane (PEM) materials, having high proton conductivity in the range of 0.061-0.209 and 0.146-0.365 S/cm at 30 and 80 degrees C (under hydrated conditions), respectively. SPAES-39 (IEC = 1.93 mequiv/g) showed higher or comparable proton conductivity than that of Nafion 117 at 50-95% RH (relative humidity). The methanol permeabilities of these membranes were in the range of 3.22 to 13.1 x 10(-7) cm(2)/s, which is lower than Nafion (15.5 x 10(-7) cm(2)/s). In comparison with some reported sulfonated poly(arylene ether sulfone)s containing pendent sulfophenyl groups, the present fluorene-based SPAES containing clustered flexible pendent aliphatic sulfonic acid groups displayed better properties, such as lower water uptake and higher proton conductivities. A combination of high proton conductivities, low water uptake, and low methanol permeabilities for selected SPAES indicates that they are good candidate proton exchange membrane materials for evaluation in fuel cell applications. | en_US |
dc.description.sponsorship | Funding for the project by the WCU program, National Research Foundation (NRF) of the Korean Ministry of Science and Technology (No.R31-2008-000-10092-0) is gratefully acknowledged. | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | Bisphenols | en_US |
dc.subject | Fluorenes | en_US |
dc.subject | Fuel cell application | en_US |
dc.subject | Hydroxyl groups | en_US |
dc.subject | Low methanol permeability | en_US |
dc.subject | Low water | en_US |
dc.subject | Methanol permeability | en_US |
dc.subject | Methanol transport | en_US |
dc.subject | Methoxy group | en_US |
dc.subject | Nafion 117 | en_US |
dc.subject | Overall properties | en_US |
dc.subject | Poly(arylene ether sulfone) | en_US |
dc.subject | Polymer electrolyte membranes | en_US |
dc.subject | Proton exchange membranes | en_US |
dc.subject | Side-chains | en_US |
dc.subject | Sulfonated copolymer | en_US |
dc.subject | Sulfonated poly(arylene ether sulfone) | en_US |
dc.subject | Sulfonic acid | en_US |
dc.subject | Sulfonic acid groups | en_US |
dc.subject | Sulfophenyl | en_US |
dc.subject | Water uptake | en_US |
dc.title | Fluorene-Based Poly(arylene ether sulfone)s Containing Clustered Flexible Pendant Sulfonic Acids as Proton Exchange Membranes | en_US |
dc.type | Article | en_US |
dc.relation.no | 18 | - |
dc.relation.volume | 44 | - |
dc.identifier.doi | 10.1021/ma2015968 | - |
dc.relation.page | 7296-7306 | - |
dc.relation.journal | MACROMOLECULES | - |
dc.contributor.googleauthor | Guiver, Michael D. | - |
dc.contributor.googleauthor | Lee, So-Young | - |
dc.contributor.googleauthor | Shin, Dong-Won | - |
dc.contributor.googleauthor | Wang, Chenyi | - |
dc.contributor.googleauthor | Kang, Na-Rae | - |
dc.contributor.googleauthor | Lee, Young-Moo | - |
dc.contributor.googleauthor | Li, Nanwen | - |
dc.relation.code | 2011206413 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF ENERGY ENGINEERING | - |
dc.identifier.pid | ymlee | - |
dc.identifier.researcherID | 7005174147 | - |
dc.identifier.orcid | http://orcid.org/0000-0003-2619-6809 | - |
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