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Auxiliary-Controlled Asymmetric [3+2]-Dipolar Cycloaddition of Azomethine Ylides Generated from Au-Catalyzed Intramolecular Redox Reaction of Nitronyl Alkynes

Title
Auxiliary-Controlled Asymmetric [3+2]-Dipolar Cycloaddition of Azomethine Ylides Generated from Au-Catalyzed Intramolecular Redox Reaction of Nitronyl Alkynes
Author
신승훈
Keywords
[3+2] dipolar cycloaddition; chiral auxiliaries; gold; hydroxylamines; ylides
Issue Date
2011-06
Publisher
WILEY-BLACKWELL, COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA
Citation
Chemistry - An Asian Journal, Vol.6 No.8 [2011], 1977-1981
Abstract
As strong as an aux: An electronically-tuned hydroxylamine functions as an excellent chiral auxiliary for [3+2] cycloaddition of the azomethine ylides generated in-situ from gold-catalyzed redox reaction of alkynyl nitrones.
URI
http://onlinelibrary.wiley.com/doi/10.1002/asia.201100159/abstract;jsessionid=53F0DDA59A08339FD8B21C6FA97E7526.f01t04http://hdl.handle.net/20.500.11754/37228
ISSN
1861-4728
DOI
10.1002/asia.201100159
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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