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Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | 윤소원 | - |
| dc.date.accessioned | 2018-02-07T05:15:04Z | - |
| dc.date.available | 2018-02-07T05:15:04Z | - |
| dc.date.issued | 2011-07 | - |
| dc.identifier.citation | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; JUL 2011, 20-21, p3904-p3910, 7p. | en_US |
| dc.identifier.issn | 1434-193X | - |
| dc.identifier.issn | 1099-0690 | - |
| dc.identifier.uri | http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201100113/abstract | - |
| dc.identifier.uri | http://hdl.handle.net/20.500.11754/35839 | - |
| dc.description.abstract | A Au-I-catalyzed intramolecular cyclization reaction of 2-alkenylphenyl carbonyl compounds to afford a variety of indene, indenol, and indanone ring systems was developed. In this process, Au-I serves to activate the carbonyl group of beta-keto esters, aldehydes, and ketones, preferentially exhibiting oxophilicity in the presence of C-C multiple bonds. Furthermore, beta-keto esters could participate as the electrophilic partner in reactions with carbon nucleophile such as alkenes. | en_US |
| dc.description.sponsorship | This work was supported by the Mid-Career Researcher Program (No. R01-2009-008-3940) and Basic Science Research Program (Nos. 2010-0017149 and 2010-0007737) through the National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology (MEST). A.R.J. is grateful for 2009 NRF Post-doctoral Fellowship Program for Foreign Researchers (No. K20802001473-10B120004500). We gratefully acknowledge Professor Juyoung Yoon (Department of Chemistry and Nano Science, Ewha Womans University) for his generous support. We also thank Dr. Ji-Eun Lee (Central Instrument Facility, Gyeongsang National University) for X-ray crystallographic analysis and Mr. Byung Seok Kim for assistance with spectroscopic data collection and analysis. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY | en_US |
| dc.subject | Gold | en_US |
| dc.subject | Cyclization | en_US |
| dc.subject | Carbonyl compounds | en_US |
| dc.subject | Alkenes | en_US |
| dc.subject | Fused-ring systems | en_US |
| dc.title | Au-I-Catalyzed Intramolecular Cyclization of 2-Alkenylphenyl Carbonyl Compounds: Exploring the Oxophilic Lewis Acidity of Au-I Species | en_US |
| dc.type | Article | en_US |
| dc.identifier.doi | 10.1002/ejoc.201100113 | - |
| dc.relation.page | 3904-3910 | - |
| dc.relation.journal | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | - |
| dc.contributor.googleauthor | Jagdale, Arun R. | - |
| dc.contributor.googleauthor | Youn, So Won | - |
| dc.relation.code | 2011203042 | - |
| dc.sector.campus | S | - |
| dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
| dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
| dc.identifier.pid | sowony73 | - |
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