C-Na3V1.96Fe0.04(PO4)3/Fe2P nanoclusters with stable charge-transfer interface for high-power sodium ion batteries
- Title
- C-Na3V1.96Fe0.04(PO4)3/Fe2P nanoclusters with stable charge-transfer interface for high-power sodium ion batteries
- Author
- 황장연
- Keywords
- Sodium ion batteries; Metal phosphide; Nanocomposite; Na3V2(PO4)3; Fe2P
- Issue Date
- 2021-01
- Publisher
- ELSEVIER SCIENCE SA
- Citation
- CHEMICAL ENGINEERING JOURNAL, v. 404, article no. 126974
- Abstract
- In this study, we synthesize a carbon-coated Na3V1.96Fe0.04(PO4)3-Fe2P composite (NVFP-FP/C) as a cathode material using a one-pot pyro-synthesis method and demonstrate its superior sodium storage performance for sodium-ion batteries. The Na3V1.96Fe0.04(PO4)3-Fe2P composite consists of unique nanoclusters of electrically conductive ultra-fine Fe2P crystals randomly dispersed among the NVP particles. The presence of Fe2P in the composite cathode greatly enhances its electronic conductivity and Na+-ion diffusion co-efficient; hence, the NVFP-FP/C cathode exhibits a high discharge capacity of 103.2 mAh g−1 at 0.1C, remarkable long term cycling stability over 2000 cycles at 20C and excellent power capability up to 40C.
- URI
- https://www.sciencedirect.com/science/article/pii/S1385894720331028?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/175322
- ISSN
- 1385-8947; 1873-3212
- DOI
- 10.1016/j.cej.2020.126974
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ENERGY ENGINEERING(에너지공학과) > Articles
- Files in This Item:
There are no files associated with this item.
- Export
- RIS (EndNote)
- XLS (Excel)
- XML