Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유효종 | - |
dc.date.accessioned | 2022-05-11T08:03:13Z | - |
dc.date.available | 2022-05-11T08:03:13Z | - |
dc.date.issued | 2022-04 | - |
dc.identifier.citation | ACS Omega; 4/19/2022, Vol. 7 Issue 15, p13067-13074, 8p | en_US |
dc.identifier.issn | 24701343 | - |
dc.identifier.uri | https://pubmed.ncbi.nlm.nih.gov/35474782/ | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/170775 | - |
dc.description.abstract | The systematic combination of well-defined coordination spheres and multiple types of ligands (heteroleptic) can lead to the generation of hierarchical metallosupramolecules with a high level of complexity and functionality. In particular, a specific multilevel coordination-driven assembly through the initiate generation of multinuclear clusters can form unique heteroleptic multiple-stranded supramolecular complexes. Herein, we report novel triple-stranded nickel-based supramolecules constructed from two different ditopic ligands ([1,1′:3′,1′′-terphenyl]-4,4′′-dicarboxylate (TP) and 2,6-pyridinedicarboxylate (PDA)) and a nickel precursor. The solid-state structures of the as-synthesized supramolecules revealed that three PDA ligands are employed to fabricate a tetranuclear ({Ni4}) cluster, and two {Ni4} clusters are assembled to form the final triple-stranded metallosupramolecules by three TP ligands. The bridging TP ligands also provide large inner voids with highly hydrophobic environments. Structural investigation of the generated complexes provided a deeper understanding of the aspects driving the formation of heteroleptic supramolecules, which is crucial for the design of multiple-strands with desired morphologies and functionalities. | en_US |
dc.description.sponsorship | This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2020R1A2C1004006 and NRF2021R1C1C1006765). Experiments at PLS-II were supported in part by MSIP and POSTECH (2021-first-2D-019, 2021- second-2D-023, and 2021-third-2D-032). Magnetic measurements were performed using facilities at IBS Center for Correlated Electron Systems, Seoul National University. | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.title | Heteroleptic Triple-Stranded Metallosupramolecules with Hydrophobic Inner Voids | en_US |
dc.type | Article | en_US |
dc.relation.no | 15 | - |
dc.relation.volume | 7 | - |
dc.identifier.doi | 10.1021/acsomega.2c00447 | - |
dc.relation.page | 13067-13074 | - |
dc.relation.journal | ACS OMEGA | - |
dc.contributor.googleauthor | Nguyen, Thanh Nhan | - |
dc.contributor.googleauthor | Tran, Ngoc Minh | - |
dc.contributor.googleauthor | Park, In-Hyeok | - |
dc.contributor.googleauthor | Yoo, Hyojong | - |
dc.relation.code | 2022037974 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF ENGINEERING SCIENCES[E] | - |
dc.sector.department | DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING | - |
dc.identifier.pid | hjhaha73 | - |
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