Facile Green Synthesis of Pseudocapacitance-Contributed Ultrahigh Capacity Fe-2(MoO4)(3) as an Anode for Lithium-Ion Batteries
- Title
- Facile Green Synthesis of Pseudocapacitance-Contributed Ultrahigh Capacity Fe-2(MoO4)(3) as an Anode for Lithium-Ion Batteries
- Author
- 임원빈
- Keywords
- pseudocapacitance; anode; lithium-ion batteries; water droplet-assisted solid-state reaction; ultrahigh capacity
- Issue Date
- 2020-08
- Publisher
- AMER CHEMICAL SOC
- Citation
- ACS APPLIED MATERIALS & INTERFACES, v. 12, no. 31, page. 35152-35163
- Abstract
- The investigation into the use of earth-abundant elements as electrode materials for lithium-ion batteries (LIBs) is becoming more urgent because of the high demand for electric vehicles and portable devices. Herein, a new green synthesis strategy, based on a facile solid-state reaction with the assistance of water droplets' vapor, was conducted to prepare Fe-2(MoO4)(3) nanosheets as anode materials for LIBs. The obtained sample possesses a two-dimensional stacked nanosheet construction with open gaps providing a much higher surface area compared to the bulk sample conventionally synthesized. The nanosheet sample delivers an ultrahigh reversible capacity (1983.6 mA h g(-1)) at a current density of 100 mA g(-1) after 400 cycles, which could be related to the contribution of pseudocapacitance. The enhancement in cyclability and rated performance with an interesting increased capacity could be caused by the effect of electrochemical milling and the in situ formation of metallic particles in its lithium-ion storage mechanism.
- URI
- https://pubs.acs.org/doi/10.1021/acsami.0c11862https://repository.hanyang.ac.kr/handle/20.500.11754/170360
- ISSN
- 1944-8244; 1944-8252
- DOI
- 10.1021/acsami.0c11862
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > MATERIALS SCIENCE AND ENGINEERING(신소재공학부) > Articles
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