Two-dimensional, P-doped Si/SiOx alternating veneer-like microparticles for high-capacity lithium-ion battery composite
- Title
- Two-dimensional, P-doped Si/SiOx alternating veneer-like microparticles for high-capacity lithium-ion battery composite
- Author
- 조국영
- Keywords
- Li-ion battery; Si veneer-like electrode; Composite anode; SiOxbuffer layer; 2D structure
- Issue Date
- 2020-12
- Publisher
- ELSEVIER SCIENCE SA
- Citation
- CHEMICAL ENGINEERING JOURNAL, v. 402, Article no. 126292, 10pp
- Abstract
- Si is a promising candidate for next-generation anode materials in lithium rechargeable batteries as it has a high theoretical specific capacity. However, mechanical damage due to volume changes during electrochemical cycling and low electrical conductivity are critical limitations for practical anode applications. Herein, a novel microscale 2D active material with alternating layers of Si and silicon oxide is developed, and its energy storage properties are investigated by fabricating a composite anode with conventional graphite. The composite anode shows improved specific capacity by the introduction of veneer-shaped Si microparticles and 88% capacity retention after 200 charge-discharge cycles. The adequate thickness of the layers and the repeating buffering layer existence in the high aspect-ratio microscale particles that mimic a 2D nanostructure minimized the volume changes of the Si-based electrode during cycling while achieving high electrical conductivity. This strategy can provide fundamental breakthroughs in overcoming the existing limitations of Si-based materials for the development of high-energy-density active materials for Li batteries.
- URI
- https://www.sciencedirect.com/science/article/pii/S1385894720324207https://repository.hanyang.ac.kr/handle/20.500.11754/165016
- ISSN
- 1385-8947
- DOI
- 10.1016/j.cej.2020.126292
- Appears in Collections:
- COLLEGE OF ENGINEERING SCIENCES[E](공학대학) > MATERIALS SCIENCE AND CHEMICAL ENGINEERING(재료화학공학과) > Articles
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