Verification of Type-A and Type-B-HC Blinking Mechanisms of Organic–Inorganic Formamidinium Lead Halide Perovskite Quantum Dots by FLID Measurements

Abstract

Organic-inorganic halide perovskite nanocrystals or quantum dots (PQDs) are excellent candidates for optoelectronic applications, such as lasers, solar cells, light emitting diodes, and single photon sources. However, the potential applications of PQDs can expand once the photoluminescence, and in particular, the blinking behaviors of single PQDs are understood. Although the blinking of PQDs has been studied extensively recently, the underlying mechanism of the blinking behaviors is still under debate. In this study, we confirmed that type-A and type-B-HC (hot carrier) blinking, contributed to PQD blinking using their fluorescence lifetime intensity distribution (FLID). Type-B-HC blinking was experimentally confirmed for the first time for formamidinium based PQDs, and the simultaneous contributions of type-A and type-B blinking were clearly specified. Further, we related different FLID data to the ON/OFF time distribution as distinct features of different blinking types. We also emphasized that detection capability was crucial for correctly elucidating the blinking mechanism.