Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유창재 | - |
dc.date.accessioned | 2020-08-19T01:39:21Z | - |
dc.date.available | 2020-08-19T01:39:21Z | - |
dc.date.issued | 2019-07 | - |
dc.identifier.citation | LIQUID CRYSTALS, v. 46, no. 13-14, Page. 2042-2056 | en_US |
dc.identifier.issn | 0267-8292 | - |
dc.identifier.issn | 1366-5855 | - |
dc.identifier.uri | https://www.tandfonline.com/doi/full/10.1080/02678292.2019.1630492 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/152335 | - |
dc.description.abstract | New hockey-stick-shaped liquid crystals (HSLCs) have been designed and synthesised. By extreme shortening of one 'arm' in the HSLCs, we have constructed the pronounced overall hockey-stick-shaped molecular conformation of these materials, and called the pseudo-rod-like (PRL) molecules with hockey-stick-shaped mesogen. The chemical structures were identified using spectroscopy and elemental analysis. The mesomorphic behaviour was investigated by polarising optical microscopy (POM), differential scanning calorimetry (DSC), X-ray diffractometry (XRD), and via electro-optical experiments. As a result, in spite of the PRL molecules, the various mesomorphic polymorphism, the interdigitated bi-layered structure and macroscopic polarity were found. Similar to up-to-date HSLCs, the quasi-bent-core LCs showed a transition from the synclinic SmC phase (SmCs) to anticlinic SmC (SmCa) phase, and exhibited SmA-type (N-CybA) and SmC-type (N-CybC) cybotactic nematic phases. At the same time, similar to practical rod-like LCs, the PRL molecules showed good surface alignment behaviour under planar boundary conditions. | en_US |
dc.description.sponsorship | This research was supported by the Basic Science Research Program (No. NRF-2017R1D1A1B03030179) through the National Research Foundation of Korea (NRF) grants funded by the Korea government (MSIP). | en_US |
dc.language.iso | en | en_US |
dc.publisher | TAYLOR & FRANCIS LTD | en_US |
dc.subject | Polar symmetry | en_US |
dc.subject | hockey-stick liquid crystals | en_US |
dc.subject | mesophase polymorphism | en_US |
dc.subject | interdigitated bilayer structure | en_US |
dc.subject | uniform texture | en_US |
dc.title | Polar smectic phases in quasi-bent-core liquid crystals with hockey-stick-shaped mesogen: synthesis and crossover mesomorphism | en_US |
dc.type | Article | en_US |
dc.relation.no | 13-14 | - |
dc.relation.volume | 46 | - |
dc.identifier.doi | 10.1080/02678292.2019.1630492 | - |
dc.relation.page | 2042-2056 | - |
dc.relation.journal | LIQUID CRYSTALS | - |
dc.contributor.googleauthor | Choi, E-Joon | - |
dc.contributor.googleauthor | Kim, Hye-Jin | - |
dc.contributor.googleauthor | Kang, Seung-Chang | - |
dc.contributor.googleauthor | Kim, Dae-Yoon | - |
dc.contributor.googleauthor | Jeong, Kwang-Un | - |
dc.contributor.googleauthor | Lee, You-Jin | - |
dc.contributor.googleauthor | Yu, Chang-Jae | - |
dc.contributor.googleauthor | Kim, Jae-Hoon | - |
dc.relation.code | 2019001087 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF ELECTRONIC ENGINEERING | - |
dc.identifier.pid | cjyu | - |
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