Fabrication of Zinc-based Coordination Polymer Nanocubes and Post-Modification through Copper Decoration
- Title
- Fabrication of Zinc-based Coordination Polymer Nanocubes and Post-Modification through Copper Decoration
- Author
- 유효종
- Keywords
- zinc-based coordination polymer nanocubes; shape-directing modulator; size and shape controls; post-modification; heterogeneous catalytic reaction
- Issue Date
- 2018-11
- Publisher
- TSINGHUA UNIV PRESS
- Citation
- NANO RESEARCH, v. 11, No. 11, Page. 5890-5901
- Abstract
- Coordination polymer particles (CPPs) with a high degree of porosity and multi-functional reaction sites are promising for diverse applications. The integration of open sites favorable for the post-modification of CPPs presents a unique opportunity for the rational design of inorganic materials with target-oriented functions. Herein, we report a shape-controllable synthetic protocol for zinc-based coordination polymer nanocubes (Zn-CPNs). In the synthesis, 2,6-bis[(4-carboxyanilino)carbonyl] pyridine ([N3]) ligand is employed as an efficient shape-directing modulator to control the size and shape of Zn-CPNs. More importantly, the [N3] ligand provides metal binding sites suitable for the decoration of other functional metals such as copper ions. The copper-modified Zn-CPNs (Cu_Zn-CPNs) show good activities in a heterogeneous catalytic reaction.
- URI
- https://link.springer.com/article/10.1007%2Fs12274-018-2098-5https://repository.hanyang.ac.kr/handle/20.500.11754/121409
- ISSN
- 1998-0124; 1998-0000
- DOI
- 10.1007/s12274-018-2098-5
- Appears in Collections:
- COLLEGE OF ENGINEERING SCIENCES[E](공학대학) > MATERIALS SCIENCE AND CHEMICAL ENGINEERING(재료화학공학과) > Articles
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