Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유효종 | - |
dc.date.accessioned | 2019-12-26T01:37:58Z | - |
dc.date.available | 2019-12-26T01:37:58Z | - |
dc.date.issued | 2018-08 | - |
dc.identifier.citation | CHEMISTRY-AN ASIAN JOURNAL, v. 13, No. 15, Page. 1915-1919 | en_US |
dc.identifier.issn | 1861-4728 | - |
dc.identifier.issn | 1861-471X | - |
dc.identifier.uri | https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201800837 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/121399 | - |
dc.description.abstract | Metallosupramolecule-based polymeric platforms with high degrees of hierarchy and tailorable functionalities are of great interests because of their unique morphologies and potential applications. Herein, the controllable synthesis of a highly-ordered polymeric structure, {[M,P-Co-8(PDA)(6)(HIP)(3)(DMF)(5)(H2O)](3)-[Co(DMF)(H2O)(2)]} (1) (PDA=2,6-pyridinedicarboxylate, HIP=5-hydroxyisophthalate, DMF=dimethylformamide) with unique topology is reported. The solid-state structure of 1 reveals that it is alternately and periodically assembled from racemic supramolecular monomers to form a zigzag-shaped polymeric strand. Discrete racemic supramolecules (2) with topologies similar to those of monomeric species of 1 are also controllably synthesized in a separate reaction. Formation of intermolecular hydrogen bonds between supramolecules associated with hydroxyl groups of HIPs are critical for the unique solid-state packing geometries of 1 and 2. | en_US |
dc.description.sponsorship | This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2015R1A4A1041631 and NRF-2016R1A2B4009281). This work was supported by the Hallym University Postdoctoral Fellowship Program of 2017 (HLM-PF-2017-0003, Dr. Hien Duy Mai). Experiments at PLS-II were supported in part by MSIP and POSTECH (2018-1st-2D-026). Magnetic measurements were performed using facilities at IBS Center for Correlated Electron Systems, Seoul National University. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | WILEY-V C H VERLAG GMBH | en_US |
dc.subject | highly-ordered assembly | en_US |
dc.subject | intermolecular hydrogen bond | en_US |
dc.subject | polymeric structures | en_US |
dc.subject | racemic supramolecules | en_US |
dc.title | Controllable Synthesis of a Highly Ordered Polymeric Structure Assembled from Cobalt-Cluster-based Racemic Supramolecules | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1002/asia.201800837 | - |
dc.relation.journal | CHEMISTRY-AN ASIAN JOURNAL | - |
dc.contributor.googleauthor | Mai, Hien Duy | - |
dc.contributor.googleauthor | Lee, Inme | - |
dc.contributor.googleauthor | Yoo, Hyojong | - |
dc.relation.code | 2018001106 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF ENGINEERING SCIENCES[E] | - |
dc.sector.department | DEPARTMENT OF MATERIALS SCIENCE AND CHEMICAL ENGINEERING | - |
dc.identifier.pid | hjhaha73 | - |
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