Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 한성환 | - |
dc.date.accessioned | 2019-12-08T19:12:30Z | - |
dc.date.available | 2019-12-08T19:12:30Z | - |
dc.date.issued | 2018-08 | - |
dc.identifier.citation | JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 823, page. 176-183 | en_US |
dc.identifier.issn | 1572-6657 | - |
dc.identifier.issn | 1873-2569 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S1572665718304211?via%3Dihub | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/119704 | - |
dc.description.abstract | In this work, we fabricated copper-1, 3, 5-benzenetricarboxylate framework nanocrystals on polyaniline (nano-Cu-BTCs/PANI) composites via a Layer-by-Layer (LbL) method. By increasing the number of LbL cycles, size and amount of the nano-Cu-BTCs in the composites were increased. The composite with more amounts of nano-Cu-BTCs exhibited larger surface areas and more increased electrical resistivity. The composites were investigated as electrocatalysts for oxygen reduction reaction (ORR) in 0.1 M KOH. Among the nano-Cu-BTCs(x wt%)/PANI (x = 8.2, 12, 20, and 37) composites, the composite with 12 wt% of Cu-BTC nanocrystals showed the best electrocatalytic activity for ORR, which would be mainly associated with destabilization of a OH2- intermediate, resulting in a further reduction reaction of the intermediate to OH- in the alkaline solution. | en_US |
dc.description.sponsorship | This work was supported by the Basic Science Research Program (2016R1D1A1A09919814) through the National Research Foundation (NRF) of Korea and the Creative Materials Discovery Program on Creative Multilevel Research Center (2015M3D1A1068061) through the NRF of Korea funded by the Ministry of Science, ICT and Future Planning. This work was also funded by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2015R1C1A1A01052368). | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | ELSEVIER SCIENCE SA | en_US |
dc.subject | Metal organic framework | en_US |
dc.subject | Nanocrystal | en_US |
dc.subject | Layer-by-layer deposition | en_US |
dc.subject | Electrocatalysis | en_US |
dc.subject | Oxygen reduction reaction | en_US |
dc.title | Copper-1, 3, 5-benzenetricarboxylate framework nanocrystals on polyaniline: Fabrication, characteristics, and electrochemical application for oxygen reduction reaction | en_US |
dc.type | Article | en_US |
dc.relation.volume | 823 | - |
dc.identifier.doi | 10.1016/j.jelechem.2018.06.006 | - |
dc.relation.page | 176-183 | - |
dc.relation.journal | JOURNAL OF ELECTROANALYTICAL CHEMISTRY | - |
dc.contributor.googleauthor | Cho, Keumnam | - |
dc.contributor.googleauthor | Shin, Chan-Yong | - |
dc.contributor.googleauthor | Leem, Yun Jin | - |
dc.contributor.googleauthor | Sung, Myung Mo | - |
dc.contributor.googleauthor | Chang, Jinho | - |
dc.contributor.googleauthor | Han, Sung-Hwan | - |
dc.relation.code | 2018001503 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | shhan | - |
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