Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 서영웅 | - |
dc.date.accessioned | 2019-12-05T06:33:19Z | - |
dc.date.available | 2019-12-05T06:33:19Z | - |
dc.date.issued | 2018-02 | - |
dc.identifier.citation | CHEMSUSCHEM, v. 11, no. 4, page. 661-665 | en_US |
dc.identifier.issn | 1864-5631 | - |
dc.identifier.issn | 1864-564X | - |
dc.identifier.uri | https://onlinelibrary.wiley.com/doi/abs/10.1002/cssc.201702256 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/117438 | - |
dc.description.abstract | The liquid organic hydrogen carrier (LOHC) 2-(N-methylbenzyl)pyridine (MBP) shows good potential for H-2 storage based on reversible hydrogenation and dehydrogenation, with an H-2 storage density of 6.15wt%. This material and the corresponding perhydro product (H-12-MBP) are liquids at room temperature. Remarkably, H-2 release is much faster from H-12-MBP over Pd/C than from the benchmark perhydro benzyltoluene over Pt/C at lower temperatures than 270 degrees C, owing to the addition of N atom into the benzene ring. Since this positive effect is unfavorable to the hydrogenation reaction, more Ru/Al2O3 catalyst or prolonged reaction time must be applied for complete H-2 storage. Experiments with repeated hydrogenation-dehydrogenation cycles reveal that reversible H-2 storage and release are possible without degradation of the MBP/H-12-MBP pair. The prepared MBP satisfies the requirements for chemical stability, handling properties, and cytotoxicity testing. | en_US |
dc.description.sponsorship | This work was financially supported by the Korea Institute of Energy Technology Evaluation and Planning under the Ministry of Trade, Industry & Energy, Republic of Korea (KETEP-2017-3030041360) and by the Basic Science Research Program through the National Research Foundation of Korea under the Ministry of Education, Republic of Korea (NRF-2016R1A6A1A03013422). | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | WILEY-V C H VERLAG GMBH | en_US |
dc.subject | dehydrogenation | en_US |
dc.subject | heterocycles | en_US |
dc.subject | hydrogen storage | en_US |
dc.subject | sustainable chemistry | en_US |
dc.title | 2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H-2 Release and Stable Activity in Consecutive Cycles | en_US |
dc.type | Article | en_US |
dc.relation.no | 4 | - |
dc.relation.volume | 11 | - |
dc.identifier.doi | 10.1002/cssc.201702256 | - |
dc.relation.page | 661-665 | - |
dc.relation.journal | CHEMSUSCHEM | - |
dc.contributor.googleauthor | Oh, Jinho | - |
dc.contributor.googleauthor | Jeong, Kwanyong | - |
dc.contributor.googleauthor | Kim, Tae Wan | - |
dc.contributor.googleauthor | Kwon, Hyunguk | - |
dc.contributor.googleauthor | Han, Jeong Woo | - |
dc.contributor.googleauthor | Park, Ji Hoon | - |
dc.contributor.googleauthor | Suh, Young-Woong | - |
dc.relation.code | 2018000630 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL ENGINEERING | - |
dc.identifier.pid | ywsuh | - |
dc.identifier.orcid | http://orcid.org/0000-0002-2094-0724 | - |
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