Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 조천규 | - |
dc.date.accessioned | 2019-12-02T02:25:00Z | - |
dc.date.available | 2019-12-02T02:25:00Z | - |
dc.date.issued | 2017-11 | - |
dc.identifier.citation | ORGANIC LETTERS, v. 19, no. 22, page. 6168-6171 | en_US |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.issn | 1523-7052 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.orglett.7b03078 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/116217 | - |
dc.description.abstract | A conceptually new synthetic approach that provides general access to the aspidosperma alkaloids (+)-aspidospermidine and (-)-tabersonine was developed. This method is based on the regioselective indolization of an ene-hydrazide, which was obtained via a base-catalyzed intramolecular aza-Michael reaction, in situ trapping of the resulting enolate, and subsequent C-N coupling with phenyl hydrazide. | en_US |
dc.description.sponsorship | This work was supported by a grant from the National Research Foundation of Korea (2014R1A5A1011165). We also thank Dr. Hyun-Kyu Cho (SK Innovation) for the initial contribution. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | BIOMIMETIC ALKALOID SYNTHESES | en_US |
dc.subject | ASPIDOSPERMA ALKALOIDS | en_US |
dc.subject | ALLYLIC OXIDATION | en_US |
dc.subject | PRIMARY ALCOHOLS | en_US |
dc.subject | INDOLE SYNTHESIS | en_US |
dc.subject | (+/-)-ASPIDOSPERMIDINE | en_US |
dc.subject | (-)-ASPIDOSPERMIDINE | en_US |
dc.subject | (-)-VINCADIFFORMINE | en_US |
dc.subject | (+/-)-TABERSONINE | en_US |
dc.subject | REARRANGEMENT | en_US |
dc.title | Directed Fischer Indolization as an Approach to the Total Syntheses of (+)-Aspidospermidine and (-)-Tabersonine | en_US |
dc.type | Article | en_US |
dc.relation.no | 22 | - |
dc.relation.volume | 19 | - |
dc.identifier.doi | 10.1021/acs.orglett.7b03078 | - |
dc.relation.page | 6168-6171 | - |
dc.relation.journal | ORGANIC LETTERS | - |
dc.contributor.googleauthor | Kim, Joo-Young | - |
dc.contributor.googleauthor | Suhl, Chang-Heon | - |
dc.contributor.googleauthor | Lee, Joon-Ho | - |
dc.contributor.googleauthor | Cho, Cheon-Gyu | - |
dc.relation.code | 2017001238 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | ccho | - |
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