Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 나명수 | - |
dc.date.accessioned | 2019-08-13T02:43:34Z | - |
dc.date.available | 2019-08-13T02:43:34Z | - |
dc.date.issued | 2006-09 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v. 45, No. 20, Page. 7991-7993 | en_US |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/ic060646d | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/108519 | - |
dc.description.abstract | A novel S-4-symmetric icosanuclear manganese metalladiazamacrocycle was synthesized using a pentadentate ligand, N-3-phenyl-trans-2- propenoylsalicylhydrazide (H3L), that has a rigid and bulky terminal N-acyl group. A 20 cyclic repeat of an -(Mn-N-N)-linkage resulted in a highly puckered diaza-bridged 60-membered icosanuclear metallamacrocycle. The steric interaction between the ligands in the cyclic system leads to five consecutive Mn-III centers in a chemically different -(MnAMnBMnCMnDMnE)- environment, with the chiralities of the metal centers being in a rather complicated -(Lambda Lambda Delta Lambda Lambda)(Delta Delta Lambda Delta Delta)- sequence. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.title | Steric control of a bridging ligand for high nuclearity metallamacrocycle formation: A highly puckered 60-membered icosanuclear metalladiazamacrocycle | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/ic060646d | - |
dc.relation.journal | INORGANIC CHEMISTRY | - |
dc.contributor.googleauthor | Moon, Dohyun | - |
dc.contributor.googleauthor | Lee, Kyungjae | - |
dc.contributor.googleauthor | John, Rohith P. | - |
dc.contributor.googleauthor | Kim, Ghyung Hwa | - |
dc.contributor.googleauthor | Suh, Byoung Jin | - |
dc.contributor.googleauthor | Lah, Myoung Soo | - |
dc.relation.code | 2009204045 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE & TECHNOLOGY[E] | - |
dc.sector.department | DIVISION OF SCIENCE & TECHNOLOGY | - |
dc.identifier.pid | mslah | - |
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